143879-49-6Relevant articles and documents
Ruthenium-amido complexes: Synthesis, structure, and catalytic activity in olefin metathesis
Pietraszuk, Cezary,Rogalski, Szymon,Powala, Beata,Mietkiewski, Milosz,Kubicki, MacIej,Spolnik, Grzegorz,Danikiewicz, Witold,Wozniak, Krzysztof,Pazio, Aleksandra,Szadkowska, Anna,Kozlowska, Anna,Grela, Karol
, p. 6465 - 6469 (2012)
Unprecedented amido derivatives of the first-, second-, and third-generation Grubbs ruthenium catalysts were prepared, characterized, and tested in ring-closing metathesis (RCM) of model dienes. In the ruthenium-amide (formally: 2-ruthenaindole) form, the
Ruthenium Amide Complexes – Synthesis and Catalytic Activity in Olefin Metathesis and in Ring-Opening Polymerisation
Gawin, Anna,Pump, Eva,Slugovc, Christian,Kajetanowicz, Anna,Grela, Karol
, p. 1766 - 1774 (2018/05/14)
A set of olefin metathesis catalysts bearing a ruthenium amide moiety was synthesised. In the ruthenium amide form these complexes exhibit very low activity in standard metathesis reactions. However, a dramatic increase of activity was observed upon in si
Ortho-Vinylation reaction of anilines
Yamaguchi, Masahiko,Arisawa, Mieko,Hirama, Masahiro
, p. 1399 - 1400 (2007/10/03)
N-Alkylanilines and anilines are vinylated at the ortho-position with ethyne in the presence of SnCl4-Bu3N.
Synthesis of Indoles via Amidoselenation
Izumi, Taeko,Sugano, Miwa,Konno, Touru
, p. 899 - 904 (2007/10/02)
The reaction of 2-styrylacetanilides (2) with N-phenylselenosuccinimide affords 1-N-acetyl-2-phenyl-3-phenylselenoindoles (3) and 1-N-acetyl-2-phenylindoles (4).The reaction of 2-vinylacetanilides (5) with phenylselenenyl bromide proceeds to form indoles via an intramolecular amidoselenation.
