Synthetic studies toward the total synthesis of kaitocephalin 1, whose stereochemical assignment was undetermined at the time of commencement, were undertaken in an attempt to provide a general methodology to gain access to any one of all 32 possible stereoisomers. An interesting, unexpected, result was observed in the anticipated stereoselective key aldol reaction.
Loh, Teck-Peng,Chok, Yew-Keong,Yin, Zheng
p. 7893 - 7897
(2007/10/03)
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