TRAPPING OF REACTIVE INTERMEDIATES IN DIENONE PHOTOCHEMISTRY BY AMINES
Irradiation of 4-methyl-4-trichloromethyl-2,5-cyclohexadienones in amine solvents leads to the formation of the corresponding dichloromethyl cyclohexadienones by a process involving electron transfer from the amines to zwitterion intermediates.
Brisimitzakis, Angelo C.,Schuster, David I.
p. 4535 - 4538
(2007/10/02)
PHOTOCHEMICAL ELECTRON TRANSFER REACTIONS OF 4-TRICHLOROMETHYL-4-METHYL-2,5-CYCLOHEXADIEN-1-ONES
Ultraviolet irradiation of the title compounds in amine solvents results in transformations attributed to initial formation of radical ions by electron transfer, the quantum efficiency of reaction depending on the ionization potential of the amine.
Schuster, David I.,Brisimitzakis, Angelo C.
p. 4531 - 4534
(2007/10/02)
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