147951-24-4Relevant articles and documents
Imidazole-based dithienylethenes as a selective chemosensors for iron(III) ions
Huang, Shuyuan,Li, Ziyong,Li, Sisi,Yin, Jun,Liu, Shenghua
scheme or table, p. 961 - 966 (2012/04/04)
Four novel imidazole-based dithienylethenes have been successfully synthesized in good yields. Their structures have been confirmed by NMR spectrometry, mass spectrometry, and elemental analyses. UV/Vis absorption spectra indicated that these dithienylethenes can easily isomerize between the open-ring and closed-ring isomers upon irradiation with UV or visible light in solution, and that the respective closed-ring isomers show decreased fluorescence properties compared with the open-ring isomers. Moreover, the open-ring and closed-ring isomers display high selectivity toward Fe 3+, such that the addition of Fe3+ obviously suppresses their fluorescence intensity.
Aldol Reactions of γ- and ε-Methylene in 5-Membered Heteroaromatic Compounds
Lee, Chang Kiu,Gong, Jin Soon,Lee, In-Sook Han
, p. 239 - 242 (2007/10/02)
5-Methyl-2-thiophenecarboxaldehyde (1a) and 3-methyl-2-thiophenecarboxaldehyde (6) underwent intermolecular aldol reactions in which the methyl group behaved as active methylene in the presence of potassium cyanide. 5-Methylfurfural (1b) gave only 5,5'-di