152194-39-3

Basic information

• Product Name: 6-DIPHENYLPHOSPHINO-2,2'-BIPYRIDINE
• Synonyms: 6-DIPHENYLPHOSPHINO-2,2'-BIPYRIDINE
• CAS NO: 152194-39-3
• Molecular Formula: C₂₂H₁₇N₂P
• Molecular Weight: 340.36
• Mol File: 152194-39-3.mol

Chemical Properties

• Boiling Point: 493.9±35.0 °C(Predicted)
• Appearance: /
• PKA: 3.75±0.22(Predicted)
• CAS DataBase Reference: 6-DIPHENYLPHOSPHINO-2,2'-BIPYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-DIPHENYLPHOSPHINO-2,2'-BIPYRIDINE(152194-39-3)
• EPA Substance Registry System: 6-DIPHENYLPHOSPHINO-2,2'-BIPYRIDINE(152194-39-3)

Safety Data

• Hazardous Substances Data: 152194-39-3(Hazardous Substances Data)

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 13040-77-2 6-Chloro-[2,2']bipyridinyl 
• 110-86-1 pyridine 
• 37943-90-1 2-(diphenylphosphino)pyridine 
• 154928-15-1 1-methyl-2,2'-bipyridine-6-one 
• 77972-47-5 1-methyl-2-(2′-pyridyl)pyridinium iodide 

Downstream Products

• 194982-97-3 [Ru₂(O₂CCH₃)2(CO)4(C₂₂H₁₇N₂P)2] 
• 194982-96-2 [Ru₂(OCHO)2(CO)4(C₂₂H₁₇N₂P)2] 
• 194982-98-4 [Ru₂(O₂CC₂H₅)2(CO)4(C₂₂H₁₇N₂P)2] 
• 1291092-85-7 cis-Re(κ1(P)-6-(diphenylphosphino)-2,2'-bipyridine)(CO)4(Br) 
• 1291092-87-9 cis-Re(κ1(P)-6-(diphenylphosphino)-2,2'-bipyridine)(CO)4(Me) 
• 1291093-05-4 Re(6-(diphenylphosphino)-2,2'-bipyridine)(CO)4(COEt) 
• 1291092-89-1 [Re(κ1(P)-6-(diphenylphosphino)-2,2'-bipyridine*ZnMe)(μ2-COMe)(CO)4][OTf] 
• 1291093-02-1 [Re(κ1(P)-6-(diphenylphosphino)-2,2'-bipyridine*ZnEt)(CO)4(COEt)][OTf] 
• 1291093-04-3 [Re(κ1(P)-6-(diphenylphosphino)-2,2'-bipyridine*ZnBn)(CO)4(COBn)][OTf] 

Relevant articles and documents

Regioselective functionalisation of 2-(diphenylphosphino)pyridine: Direct lithiation at the pyridine C-6 position

It is shown that 2-(diphenylphosphino)pyridine was efficiently and regioselectively metallated at the C-6 position by use of the BuLi- Me2N(CH2)2OLi basic system. The method described opened access to various functionally

Synthesis and molecular structure of the potentially binucleating tridentate ligand 6-diphenylphosphino-2,2'-bipyridyl

An improved procedure for the synthesis of 6-chloro-2,2'-bipyridyl from 2,2'-bipyridine is described.Treatment of this compound with LiPPh2 leads to the formation of the new, potentially binucleating tridentate ligand, 6-diphenylphosphino-2,2'-bipyridyl.The spectroscopic properties of this ligand and its molecular structure, as established by X-ray crystallography, are described.