Gold(I)-catalyzed asymmetric aldol reactions of isocyanoacetic acid derivatives with fluoroaryl aldehydes
The catalytic asymmetric synthesis of stereochemically defined fluoro-phenylserines is reported. In the title reaction, when methyl isocyanoacetate is employed, the number of fluorine atoms in the phenyl ring of benzaldehyde controls stereochemical outcom
Gold(I)-catalyzed asymmetric aldol reactions of fluorinated benzaldehydes with an α-isocyanoacetamide
The use of N,N-dimethyl-α-isocyanoacetamide instead of methyl α-isocyanoacetate in the gold(I)-catalyzed asymmetric aldol reactions with polyfluorinated benzaldehydes was found to improve both diastereo- and enantioselectivity in the formation of trans-ox
Soloshonok,Hayashi
p. 1091 - 1094
(2007/10/02)
More Articles about upstream products of 157042-75-6