cas 162283-20-7, Quinoline, 2-methyl-4-[(trimethylsilyl)oxy]- (9CI)

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A type II polyketide synthase from the gram-negative bacterium Stigmatella aurantiaca is involved in aurachin alkaloid biosynthesis
A closer look: The path for the biosynthesis of aurachin alkaloids (aurachin A is shown) has been deduced by molecular biological methods, including the cloning and sequencing of the biosynthetic gene cluster in the bacterium Stigmatella aurantiaca. The gene cluster encodes a type II polyketide synthase, which was discovered in this form for the first time in a Gram-negative bacterium. (Chemical Equation Presented).
Sandmann, Axel,Dickschat, Jeroen,Jenke-Kodama, Holger,Kunze, Brigitte,Dittmann, Elke,Mueller, Rolf
p. 2712 - 2716
(2007)
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Alkylation of 2-, 4-, and 8-Trialkylsiloxyquinolines by Methyl Iodide
Trimethyl- and triethylsilyl ethers of 2-, 4-, and 8-hydroxyquinolines have been prepared.The alkylation of these siloxyquinolines by methyl iodide has been studied.In the case of 4-trimethylsiloxyquinaldine, it has been established that both N- and O-alkylation products are formed.
Lukevits, E.,Segal, I.,Birgele, I.,Zablotskaya, A.
p. 1061 - 1066
(2007/10/03)