166583-62-6

Basic information

• Product Name: 1-Cyclohexene-1-carboxaldehyde,3-hydroxy-4-(1-methylethyl)-,(3S,4R)-(9CI)
• Synonyms: 1-Cyclohexene-1-carboxaldehyde,3-hydroxy-4-(1-methylethyl)-,(3S,4R)-(9CI)
• CAS NO: 166583-62-6
• Molecular Formula: C10H16O2
• Molecular Weight: 168.23
• Product Categories: ISOPROPYL
• Mol File: 166583-62-6.mol

Chemical Properties

• Boiling Point: 281.6±40.0 °C(Predicted)
• Appearance: /
• Density: 1.096±0.06 g/cm3(Predicted)
• PKA: 14.34±0.60(Predicted)
• CAS DataBase Reference: 1-Cyclohexene-1-carboxaldehyde,3-hydroxy-4-(1-methylethyl)-,(3S,4R)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-carboxaldehyde,3-hydroxy-4-(1-methylethyl)-,(3S,4R)-(9CI)(166583-62-6)
• EPA Substance Registry System: 1-Cyclohexene-1-carboxaldehyde,3-hydroxy-4-(1-methylethyl)-,(3S,4R)-(9CI)(166583-62-6)

Safety Data

• Hazardous Substances Data: 166583-62-6(Hazardous Substances Data)

Upstream product

• 2158-59-0 cryptone 
• 23963-70-4 (S)-4-Isopropyl-cyclohex-1-enecarbaldehyde 
• 18031-40-8 (S)-(-)-perillaldehyde 
• 147729-85-9 2α-isopropyl-8-oxabicyclo[3.2.1]oct-6-ene 

Relevant articles and documents

Absolute configuration of a new mosquito repellent, (+)-eucamalol and the repellent activity of its epimer.

(+)-Eucamalol (1) and (-)-1-epi-eucamalol (2) were synthesized from (S)-(-)-perillaldehyde to determine the absolute configuration of 1, the structure of natural (+)-eucamalol being determined to be (1R,6R)-(+)-3-formyl-6-isopropyl-2-cyclohexen-1-ol. (+)-

Novel Rearrangement of 2α-Isopropyl-8-oxabicyclooct-6-ene Producing the Monoterpene 3-Hydroxyphellandral

We describe a five-step synthesis of 2α-isopropyl-8-oxabicyclooct-6-ene from 1,1,3,3-tetrabromo-4-methylpentan-2-one, and its unexpected rearrangement to yield trans-3-hydroxy-4-isopropylcyclohex-1-enecarbaldehyde (3-hydroxyphellandral).