168105-32-6

Basic information

• Product Name: 2-C-(2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosyl) ethyne
• Synonyms: 2-C-(2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosyl) ethyne;3,7-Anhydro-1,2-dideoxy-D-glycero-D-gulo-oct-1-ynitol tetraacetate
• CAS NO: 168105-32-6
• Molecular Formula: C₁₆H₂₀O₉
• Molecular Weight: 356.3246
• Mol File: 168105-32-6.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-C-(2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosyl) ethyne(CAS DataBase Reference)
• NIST Chemistry Reference: 2-C-(2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosyl) ethyne(168105-32-6)
• EPA Substance Registry System: 2-C-(2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosyl) ethyne(168105-32-6)

Safety Data

• Hazardous Substances Data: 168105-32-6(Hazardous Substances Data)

Upstream product

• 141196-28-3 trimethyl(((2S,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)-tetrahydro-2H-pyran-2-yl)ethynyl)silane 
• 59531-24-7 2,3,4,6-tetra-O-benzyl-D-glucopyranoside 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 108-24-7 acetic anhydride 
• 168253-07-4 (2R,3R,4R,5S,6S)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-ethynyl-tetrahydro-pyran 

Downstream Products

• 1355034-97-7 C₂₇H₂₈FN₃O₉S 
• 1355034-98-8 C₁₉H₂₀FN₃O₅S 
• 1355034-75-1 C₂₄H₂₉N₃O₉ 
• 1355034-76-2 C₁₆H₂₁N₃O₅ 
• 1355034-86-4 C₁₆H₂₁N₃O₆ 
• 1355034-78-4 C₁₅H₁₈ClN₃O₅ 
• 1355034-90-0 C₁₅H₁₈N₄O₇ 
• 1355034-92-2 C₁₆H₁₈N₄O₅ 
• 1355034-74-0 C₁₅H₁₉N₃O₅ 
• 1355034-80-8 C₁₆H₁₈F₃N₃O₅ 
• 1355034-84-2 C₁₅H₁₈FN₃O₅ 

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167. Oligosaccharide analogues of polysaccharides: Part 9. Synthesis and thermolysis of acetylenosaccharide-derived 1,2-dialkynylbenzenes

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15. Oligosaccharide Analogues of Polysaccharides. Part 2. Regioselective Deprotection of Monosaccharide-Derived Monomers and Dimers

The Me3Si-C(1) bond of the bis-(trimethylsilyl)ethynylated anhydroalditol 2 is selectively cleaved with BuLi to yield 3/4, while AgNO2/KCN in MeOH cleaves the Me3Si-C(2') bond, leading to 5 (Scheme 1).Both Me3Si groups are removed with NaOH in MeOH (->7),