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4-(2,4,5-tripyridin-4-ylphenyl)pyridine, commonly referred to as TPPP, is a synthetic chemical compound characterized by a pyridine core with three pyridyl groups attached to a single phenyl group. This unique molecular structure endows TPPP with distinctive electronic and photophysical properties, making it a versatile material for various applications in the field of organic semiconductors.

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  • 170165-81-8 Structure
  • Basic information

    1. Product Name: 4-(2,4,5-tripyridin-4-ylphenyl)pyridine
    2. Synonyms: 4-(2,4,5-tripyridin-4-ylphenyl)pyridine;1,2,4,5-tetra(pyridin-4-yl) benzene
    3. CAS NO:170165-81-8
    4. Molecular Formula: C26H18N4
    5. Molecular Weight: 386.44792
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 170165-81-8.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 529.1±45.0 °C(Predicted)
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: 1.194±0.06 g/cm3(Predicted)
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. PKA: 4.87±0.10(Predicted)
    10. CAS DataBase Reference: 4-(2,4,5-tripyridin-4-ylphenyl)pyridine(CAS DataBase Reference)
    11. NIST Chemistry Reference: 4-(2,4,5-tripyridin-4-ylphenyl)pyridine(170165-81-8)
    12. EPA Substance Registry System: 4-(2,4,5-tripyridin-4-ylphenyl)pyridine(170165-81-8)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 170165-81-8(Hazardous Substances Data)

170165-81-8 Usage

Uses

Used in Organic Light-Emitting Diodes (OLEDs):
TPPP is utilized as a key component in the development of OLEDs due to its favorable energy levels and strong light absorption properties. Its incorporation enhances the efficiency and performance of these devices, contributing to brighter and more stable light emission.
Used in Photovoltaic Devices:
In the realm of photovoltaics, TPPP serves as a promising material for the construction of organic solar cells. Its high electron mobility and good thermal stability are crucial for improving the efficiency and durability of these devices, making them more viable for commercial applications.
Used in Organic Semiconductors:
TPPP's unique properties also make it a valuable material for the development of organic semiconductors. Its potential use in this field is currently being explored, with research focusing on harnessing its electronic and photophysical characteristics to create more efficient and versatile semiconductor materials.
Used in Organic Photodetectors:
Furthermore, TPPP has been investigated for its potential application in organic photodetectors. Its strong light absorption and favorable energy levels make it a candidate for improving the sensitivity and performance of these devices, which are essential components in various imaging and sensing technologies.

Check Digit Verification of cas no

The CAS Registry Mumber 170165-81-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,0,1,6 and 5 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 170165-81:
(8*1)+(7*7)+(6*0)+(5*1)+(4*6)+(3*5)+(2*8)+(1*1)=118
118 % 10 = 8
So 170165-81-8 is a valid CAS Registry Number.

170165-81-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-(2,4,5-tripyridin-4-ylphenyl)pyridine

1.2 Other means of identification

Product number -
Other names Pyridine,4,4',4'',4'''-(1,2,4,5-benzenetetrayl)tetrakis

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:170165-81-8 SDS

170165-81-8Downstream Products

170165-81-8Relevant articles and documents

A novel anion-pillared metal-organic framework for highly efficient separation of acetylene from ethylene and carbon dioxide

Qian, Quan-Li,Gu, Xiao-Wen,Pei, Jiyan,Wen, Hui-Min,Wu, Hui,Zhou, Wei,Li, Bin,Qian, Guodong

, p. 9248 - 9255 (2021)

Separation of acetylene (C2H2) from ethylene (C2H4) and carbon dioxide (CO2) is of great importance in the petrochemical industry but remains a daunting challenge due to their very similar sizes and physical properties. Although a number of porous materials have been developed as promising adsorbents for either C2H2/C2H4or C2H2/CO2separation, few materials exhibit simultaneously high selectivities for both gas mixtures. Herein, we report the use of a four-connected N-donor organic linker to construct a novel water-stable SIFSIX-type material, [Cu(TPB)SiF6]n(termed ZJU-280, TPB = 1,2,4,5-tetra(pyridin-4-yl)benzene). This material features suitable rhombic pores and functional surfaces to interact optimally with C2H2molecules, affording high C2H2capture capacity and simultaneously high C2H2/CO2(18.1) and C2H2/C2H4(44.5) selectivities under ambient conditions. Theoretical calculations indicate that the suitable rhombic pores and functional sites can provide a multipoint binding environment to not only preferentially interact with C2H2but also enable the dense packing of C2H2molecules within the framework. Actual breakthrough experiments demonstrate that ZJU-280a can efficiently separate C2H2from C2H2/CO2(50/50, v/v) and C2H2/C2H4(1/99 and 50/50) mixtures, respectively.

ELECTROCHROMIC COMPOUNDS AND OPTICAL ARTICLES CONTAINING THEM

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Paragraph 0.169, (2018/07/31)

Electrochromic compounds and optical articles containing them The present invention relates to a group of novel electrochromic compounds. More specifically, it relates to electrochromic compounds comprising one or several pyridinium rings and the use of these compounds as a variable transmittance medium for the manufacture of an optical article, such as an ophthalmic lens.

ORGANIC AMINE DIMMER AND METHOD FOR SYNTHESIZING THE SAME

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Page/Page column 0030-0032, (2013/12/03)

An organic amine dimmer and a method for synthesizing the same are disclosed. The method comprises the following steps: (A) mixing an iron-containing compound (e.g., Fe2O3, FeCl3), a nitrate-containing compound, oxalate ac

Structural competition between π...π interactions and halogen bonds: A crystallographic study

Ji, Baoming,Wang, Weizhou,Deng, Dongsheng,Zhang, Yu,Cao, Lei,Zhou, Le,Ruan, Chuansheng,Li, Tiesheng

, p. 769 - 774 (2013/03/29)

1,3-Diiodotetrafluorobenzene and 1,3,5-trifluoro-2,4,6-triiodobenzene form co-crystals with 4,4′,6,6′-tetramethyl-2,2′-bipyrimidine, 1,2,4,5-tetra(3-pyridyl)benzene and 1,2,4,5-tetra(4-pyridyl)benzene in which the structural competition between π...π interactions and halogen bonds is directly observed. It is found that the strong C-I...N halogen bond competes successfully with the π...π interaction between two 1,3-diiodotetrafluorobenzene molecules while the π...π interaction between two 1,3,5-trifluoro-2,4,6-triiodobenzene molecules can successfully compete with the strong C-I...N halogen bond. Quantum chemical calculations explain the structural competition well.

Palladium(O)/LiCl Promoted Cross-Coupling Reaction of (4-Pyridyl)stannanes and Aromatic Bromides: Easy Access to Poly(4-pyridyl)-Substituted Aromatics

Fujita, Makoto,Oka, Hiroko,Ogura, Katsuyuki

, p. 5247 - 5250 (2007/10/02)

A PdCl2(PPh3)2/LiCl catalyst effectively promoted the cross-coupling reaction of trimethyl(4-pyridyl)stannane and aromatic polybromides to offer easy access to poly(4-pyridyl)-substituted aromatic compounds.

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