170165-81-8Relevant articles and documents
A novel anion-pillared metal-organic framework for highly efficient separation of acetylene from ethylene and carbon dioxide
Qian, Quan-Li,Gu, Xiao-Wen,Pei, Jiyan,Wen, Hui-Min,Wu, Hui,Zhou, Wei,Li, Bin,Qian, Guodong
, p. 9248 - 9255 (2021)
Separation of acetylene (C2H2) from ethylene (C2H4) and carbon dioxide (CO2) is of great importance in the petrochemical industry but remains a daunting challenge due to their very similar sizes and physical properties. Although a number of porous materials have been developed as promising adsorbents for either C2H2/C2H4or C2H2/CO2separation, few materials exhibit simultaneously high selectivities for both gas mixtures. Herein, we report the use of a four-connected N-donor organic linker to construct a novel water-stable SIFSIX-type material, [Cu(TPB)SiF6]n(termed ZJU-280, TPB = 1,2,4,5-tetra(pyridin-4-yl)benzene). This material features suitable rhombic pores and functional surfaces to interact optimally with C2H2molecules, affording high C2H2capture capacity and simultaneously high C2H2/CO2(18.1) and C2H2/C2H4(44.5) selectivities under ambient conditions. Theoretical calculations indicate that the suitable rhombic pores and functional sites can provide a multipoint binding environment to not only preferentially interact with C2H2but also enable the dense packing of C2H2molecules within the framework. Actual breakthrough experiments demonstrate that ZJU-280a can efficiently separate C2H2from C2H2/CO2(50/50, v/v) and C2H2/C2H4(1/99 and 50/50) mixtures, respectively.
ELECTROCHROMIC COMPOUNDS AND OPTICAL ARTICLES CONTAINING THEM
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Paragraph 0.169, (2018/07/31)
Electrochromic compounds and optical articles containing them The present invention relates to a group of novel electrochromic compounds. More specifically, it relates to electrochromic compounds comprising one or several pyridinium rings and the use of these compounds as a variable transmittance medium for the manufacture of an optical article, such as an ophthalmic lens.
ORGANIC AMINE DIMMER AND METHOD FOR SYNTHESIZING THE SAME
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Page/Page column 0030-0032, (2013/12/03)
An organic amine dimmer and a method for synthesizing the same are disclosed. The method comprises the following steps: (A) mixing an iron-containing compound (e.g., Fe2O3, FeCl3), a nitrate-containing compound, oxalate ac
Structural competition between π...π interactions and halogen bonds: A crystallographic study
Ji, Baoming,Wang, Weizhou,Deng, Dongsheng,Zhang, Yu,Cao, Lei,Zhou, Le,Ruan, Chuansheng,Li, Tiesheng
, p. 769 - 774 (2013/03/29)
1,3-Diiodotetrafluorobenzene and 1,3,5-trifluoro-2,4,6-triiodobenzene form co-crystals with 4,4′,6,6′-tetramethyl-2,2′-bipyrimidine, 1,2,4,5-tetra(3-pyridyl)benzene and 1,2,4,5-tetra(4-pyridyl)benzene in which the structural competition between π...π interactions and halogen bonds is directly observed. It is found that the strong C-I...N halogen bond competes successfully with the π...π interaction between two 1,3-diiodotetrafluorobenzene molecules while the π...π interaction between two 1,3,5-trifluoro-2,4,6-triiodobenzene molecules can successfully compete with the strong C-I...N halogen bond. Quantum chemical calculations explain the structural competition well.
Palladium(O)/LiCl Promoted Cross-Coupling Reaction of (4-Pyridyl)stannanes and Aromatic Bromides: Easy Access to Poly(4-pyridyl)-Substituted Aromatics
Fujita, Makoto,Oka, Hiroko,Ogura, Katsuyuki
, p. 5247 - 5250 (2007/10/02)
A PdCl2(PPh3)2/LiCl catalyst effectively promoted the cross-coupling reaction of trimethyl(4-pyridyl)stannane and aromatic polybromides to offer easy access to poly(4-pyridyl)-substituted aromatic compounds.