18365-32-7Relevant articles and documents
CMe3SiX3 and SiMe3SiX3 (X = H, F, Cl, Br, I): A combined ab initio and vibrational spectroscopic study
Zink, Robert,Hassler, Karl
, p. 333 - 347 (2007/10/03)
The infrared and Raman vibrational spectra of the tert-butylsilanes CMe3SiX3 and disilanes SiMe3SiX3 (X = H, F, Cl, Br, I) have been measured and assigned with the help of normal coordinate analyses and potential energy distribution analyses employing ab initio optimized geometries and ab initio symmetry force constants. Scaled theoretical SiX and SiSi force constants are smaller than values estimated by extrapolation from spectroscopic force constants of related disilanes. The synthesis of the novel compound SiMe3SiI3 and the residual disilanes SiMe3SiX3 (X = H, F, Cl, Br) is described.
Preparation of oligosilanes containing perhalogenated silyl groups (-SiX3, -SiX2-, >SiX-, X = Cl, Br) and their hydrogenation by stannanes
Herzog,Roewer
, p. 217 - 223 (2007/10/03)
Starting from methylphenylsubstituted oligosilanes the disilanes SiX3-SiXi,Me3-i (i = 0, 1, 2; X = Cl, Br), trisilanes SiX2(SiXiMe3-i) (i = 0, 1) and branched tetrasilanes SiX(SiXMe2)3 were synthesized and their behavior towards the Lewis-base catalyzed hydrogenation by stannanes was investigated. In the case of methylchlorodisilanes SiCl3-SiCliMe3-i Si-Si bond cleavage competes with the hydrogenation reaction.
Shock-induced kinetics of the disilane decomposition and silylene reactions with trimethylsilane and butadiene
Dzarnoski,Rickborn,O'Neal,Ring
, p. 1217 - 1220 (2008/10/08)
The homogeneous gas-phase decomposition kinetics of disilane have been studied by the comparative rate, single-pulse shock-tube technique in the 850-1000 K (2300-2700 torr) ranges. Two primary dissociation processes occur, Si2H6-i SiH4/su
