- Three isomeric N-(nitrophenyl)succinimides: Isolated molecules, hydrogen-bonded sheets and a hydrogen-bonded three-dimensional framework
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Molecules of N-(2-nitrophenyl)succinimide, C10H 8N2O4 are linked into sheets by a combination of C-H...O and C-H...π(arene) hydrogen bonds. Molecules of N-(3-nitrophenyl)succinimide are linked into a three-dimen
- Glidewell, Christopher,Low, John N.,Skakle, Janet M.S.,Wardell, James L.
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- Controlling the selectivity of aminergic GPCR ligands from the extracellular vestibule
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In addition to the orthosteric binding pocket (OBP) of GPCRs, recent structural studies have revealed that there are several allosteric sites available for pharmacological intervention. The secondary binding pocket (SBP) of aminergic GPCRs is located in t
- Egyed, Attila,Kelemen, ádám A.,Vass, Márton,Visegrády, András,Thee, Stephanie A.,Wang, Zhiyong,de Graaf, Chris,Brea, Jose,Loza, Maria Isabel,Leurs, Rob,Keser?, Gy?rgy M.
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- Organocatalytic cascade aldimine condensation/[1,6]-hydride transfer/Mannich-type cyclization: Sustainable access to indole-2,3-fused diazocanes
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An unprecedented organocatalytic cascade aldimine condensation/[1,6]-hydride transfer/Mannich-type cyclization of indole-2-carbaldehydes with o-aminoanilines was developed to assemble polycyclic indole-2,3-fused diazocanes in one step. This novel methodol
- An, Xiao-De,Dong, Pei-Zhen,Liu, Rui-Bin,Qiu, Bin,Wang, Lin-Xuan,Xiao, Jian
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supporting information
p. 8181 - 8186
(2021/11/01)
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- Access to Polycyclic Indole-3,4-Fused Nine-Membered Ring via Cascade 1,6-Hydride Transfer/Cyclization
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A cascade aldimine condensation/1,6-hydride transfer/Mannich-type cyclization of indole-derived phenylenediamine with aldehydes was developed for one-step construction of a polycyclic indole-3,4-fused skeleton. Aldehyde serves as a key to start the whole process, including 1,6-hydride transfer enabled δ-C(sp3)-H activation of the secondary amine. The challenges of construction of medium-sized rings are addressed via hydride transfer chemistry.
- Yang, Shuo,An, Xiao-De,Qiu, Bin,Liu, Rui-Bin,Xiao, Jian
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supporting information
p. 9100 - 9105
(2021/11/24)
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- NITRATION
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The present invention relates to a process for preparing a nitrated compound, comprising the step of reacting a compound (A) comprising at least one substituted or unsubstituted aromatic or heteroaromatic ring, wherein said heteroaromatic ring comprises at least one heteroatom selected from the group consisting of oxygen, sulfur, phosphor, selenium and nitrogen, with a compound of formula (I) wherein Y is selected from the group consisting of hydrogen and nitro.
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Page/Page column 36; 37; 47; 66-67; 39; 54; 42; 67
(2020/05/28)
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