18388-42-6Relevant articles and documents
NOVEL SYNTHESIS OF β-SILOXY ESTERS BY CONDENSATION OF CARBONYLS AND TRIMETHYLSILANE WITH α,β-UNSATURATED ESTERS CATALYZED BY RhCl3
Revis, Anthony,Hilty, Terrence K.
, p. 4809 - 4812 (2007/10/02)
A novel one pot reaction of α,β-unsaturated esters with carbonyls and trimethylsilane gave good yields of β-siloxy esters.This RhCl3 catalyzed method improves upon the two step reaction of silyl ketene acetals with carbonyls.