18495-56-2Relevant articles and documents
Reactions of Isoprene with Secondary Amines
Kazantsev, O. A.,Shirshin, K. V.,Danov, S. M.,Afon'shin, G. N.
, p. 300 - 303 (2007/10/03)
Reactions of isoprene with secondary amines in the presence of alkali metals yield isomeric aminoolefins: 1-dialkylamino-3-methyl-2-butenes, 1-dialkylamino-2-methyl-2-butenes, and 1-dialkylamino-3-methyl-1-butenes.The influence of temperature, structure of the secondary amine, amount of catalyst, and molar ratio of the reactants on the yield of aminoolefins and selectivity of their formation has been examined.