18536-91-9

Basic information

• Product Name: N-DODECYLTRIETHOXYSILANE
• Synonyms: N-DODECYLTRIETHOXYSILANE;TRIETHOXYLAURYLSILANE;dodecyltriethoxy-silan;Silane,dodecyltriethoxy-;DODECYLTRIETHOXYSILANE;LAURYL TRIETHOXY SILANE;n-Diethoxytrethoxysilane;Triethoxy(dodecyl)silane
• CAS NO: 18536-91-9
• Molecular Formula: C₁₈H₄₀O₃Si
• Molecular Weight: 332.59
• EINECS: 242-409-9
• Product Categories: Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Silane Coupling Agents (Intermediates);Si-O Compounds;Trialkoxysilanes;Chemical Synthesis;Contact Printing;Materials Science;Micro/NanoElectronics;Organometallic Reagents;Organosilicon;Self Assembly &Self-Assembly Materials;Silanes;silane
• Mol File: 18536-91-9.mol

Chemical Properties

• Melting Point: <0°C
• Boiling Point: 152 °C
• Flash Point: >110°C
• Appearance: /
• Density: 0.875 g/mL at 20 °C(lit.)
• Vapor Pressure: 3.67E-05mmHg at 25°C
• Refractive Index: n20/D 1.426
• Sensitive: Moisture Sensitive
• BRN: 2414223
• CAS DataBase Reference: N-DODECYLTRIETHOXYSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: N-DODECYLTRIETHOXYSILANE(18536-91-9)
• EPA Substance Registry System: N-DODECYLTRIETHOXYSILANE(18536-91-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• F: 10-21
• TSCA: Yes
• Hazardous Substances Data: 18536-91-9(Hazardous Substances Data)

Usage

Uses

Dodecyltriethoxysilane can be used in the surface treatment of calcite crystals for the determination of the effect of wettability with the incorporation of nanoparticles. It may be electrodeposited with tetraethoxysilane, which can be used as an anti-corrosive coating on mild steel.

General Description

Dodecyltriethoxysilane (DTES) is an organosilane, which is used as a coupling agent. It forms alkylsiloxane based films that can be used to tune the wettability and facilitate a variety of surfaces with hydrophobicity.

InChI:InChI=1/C16H30O2/c1-15(17)13-11-9-7-5-3-4-6-8-10-12-14-16(2)18/h3-14H2,1-2H3

Upstream product

• 78-10-4 tetraethoxy orthosilicate 
• 15890-72-9 laurylmagnesium bromide 
• 112-41-4 1-dodecene 
• 64-17-5 ethanol 
• 998-30-1 Triethoxysilane 

Downstream Products

• 1185275-67-5 dodecylsilicic acid tris(2-phenylethyl) ester 
• 13733-78-3 dodecyl azide 
• 765-15-1 1-dodecylthiocyanate 
• 2915-72-2 dodecyl benzoate 
• 129922-44-7 1-[(trifluoromethyl)thio]dodecane 

Relevant articles and documents

MCM-41-supported mercapto platinum complex as a highly efficient catalyst for the hydrosilylation of olefins with triethoxysilane

A novel MCM-41-supported mercapto platinum complex was conveniently synthesized from commercially available and cheap γ-mercaptopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with potassium chloroplatinite. The powder X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were employed to characterize the title platinum complex. It was found that the title complex is an efficient catalyst for hydrosilylation of olefins with triethoxysilane and can be reused several times without noticeable loss of activity.

N,N-Dimethylformamide-protected Fe2O3 Combined with Pt Nanoparticles: Characterization and Catalysis in Alkene Hydrosilylation

We report a combination of N,N-dimethylformamide (DMF)-protected Fe2O3 nanoparticles (NPs) and Pt NPs for the hydrosilylation of various industrially relevant alkenes and tertiary silanes. The DMF-protected Fe2O3 and Pt NPs catalysts were characterized by transmission electron microscopy, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy. The catalyst of DMF-protected Fe2O3 NPs combined with Pt NPs can be recycled for five cycles by a simple extraction using hexane/DMF. The developed combination Fe2O3/Pt NPs catalyst is effective up to the 1-kilogram scale.

METHOD FOR PRODUCING ORGANOSILICON COMPOUND BY HYDROSILYLATION WITH METALLIC-ELEMENT-CONTAINING NANOPARTICLES

An organosilicon compound can be efficiently produced by using metallic element-containing nanoparticles such as a platinum element-containing nanoparticle having a solvent on surface as a catalyst of the hydrosilylation reaction of alkenes.

Waste-free and efficient hydrosilylation of olefins

High purity silicone precursors can now be synthesized by hydrosilylation of solvent-free olefins catalyzed by a highly stable and active glass hybrid catalyst consisting of mesoporous organosilica microspheres doped with Pt nanoparticles. These findings open the door to the sustainable manufacture of silicone and a way to further reduce the amount of platinum in silicones, which are ubiquitous advanced polymers with multiple uses and applications.

The effect of an acylphosphine ligand on the rhodium-catalyzed hydrosilylation of alkenes

We synthesized a series of acylphosphines and investigated the hydrosilylation of alkenes that were catalyzed using RhCl3/acylphosphine. The results indicated that RhCl3/(diphenylphosphino) (phenyl)methanone exhibited higher activity as well as higher levels of β–adduct selectivity.

Synthesis of a fumed silica-supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane

A novel fumed silica-supported bidentate nitrogen platinum complex was conveniently prepared from N-(2-aminoethyl)-3-aminopropyltriethoxysilane via immobilization on fumed silica followed by a reaction with hexachloroplatinic acid. The title complex was systematically characterized and analyzed by Fourier Transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and specific surface area analysis (BET). The resulting title complex was found to be efficient and stable in catalyzing the hydrosilylation reaction of olefins with triethoxysilane. Furthermore, the polymeric platinum complex could be separated by simple filtration and reused four times without any appreciable loss of catalytic activity.

Effect of triarylphosphane ligands on the rhodium-catalyzed hydrosilylation of alkene

A series of triarylphosphanes (1a, 2a, 3a, 4a, 5a, 6a, 7a, 8a, 9a, 10a, 11a) have been synthesized. An X-ray crystal structure analysis of (2-bromophenyl)diphenylphosphane (1a) unambiguously confirmed the constitution of the functionalized phosphane. The hydrosilylation reaction of styrene with triethoxysilane catalyzed with RhCl3/triarylphosphane was studied. In comparison with the classic Wilkinson's catalyst, rhodium complexes with functionalized triarylphosphane ligands are characterized by a very high catalytic effectiveness for the hydrosilylation of alkene. Among these catalysts tested, RhCl3/diphenyl(2-(trimethylsilyl)phenyl)phosphane (8a) exhibited excellent catalytic properties. Using this silicon-containing phosphane ligand for the rhodium-catalyzed hydrosilylation of styrene, both higher conversion of alkene and higher β-adduct selectivity were obtained than with Wilkinson's catalyst.

Hydrosilylation of alkenes catalyzed by rhodium with polyethylene glycol-based ionic liquids as ligands

A series of polyethylene glycol-functionalized imidazolium ionic liquids has been prepared and characterized. These ionic liquids have been successfully applied in the hydrosilylation of alkenes catalyzed by rhodium complexes. The effects of the length of the polyether chain, the amount of ionic liquid, and the reaction temperature on the catalytic performance of hydrosilylation have been investigated. Furthermore, the catalytic system has been tested for the hydrosilylation of different alkenes with triethoxysilane. The new catalytic system exhibits both excellent catalytic activity and selectivity under low-temperature conditions. The catalyst system could be recycled five times with slightly deactivation.

Study on the anti-sulfur-poisoning characteristics of platinum-acetylide- phosphine complexes as catalysts for hydrosilylation reactions

A series of platinum-acetylide-phosphine complexes were synthesized and their anti-sulfur-poisoning characteristics investigated. In comparison with Speier's and Karstedt's catalysts, the platinum-acetylide-phosphine complexes exhibited both higher catalytic activity and selectivity for the β-adduct for the hydrosilylation reactions under the same conditions. Furthermore, the complexes also exhibited a strong ability to resist to sulfur-poisoning. This indicated that the alkyne ligands containing the silyl group had a strong impact on the hydrosilylation reaction. Copyright