THERMISCHER ZERFALL VON Β-PHENYL UND Β,Β-DIPHENYL-NITROALKANEN
Elimination of nitrous acid is the exclusive reaction path for the thermal decomposition of the nitroalkanes 1, 2 and 5.Homolytic CC-cleavage cannot compete.A concerted β-elimination is the favoured mechanism.
Fritzsche, Katharina,Beckhaus, Hans-Dieter,Ruechardt, Christoph
p. 2805 - 2808
(2007/10/02)
THE ABNORMAL FINKELSTEIN REACTION. A SEQUENTIAL IONIC-FREE RADICAL REACTION MECHANISM
The reaction of alkyl halides with sodium iodide in acetone (Finkelstein Reaction) may yield coupled or rearranged products via cationic intermediates.
Smith, William B.,Branum, Gary D.
p. 2055 - 2058
(2007/10/02)
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