1860-16-8Relevant academic research and scientific papers
THERMISCHER ZERFALL VON Β-PHENYL UND Β,Β-DIPHENYL-NITROALKANEN
Fritzsche, Katharina,Beckhaus, Hans-Dieter,Ruechardt, Christoph
, p. 2805 - 2808 (2007/10/02)
Elimination of nitrous acid is the exclusive reaction path for the thermal decomposition of the nitroalkanes 1, 2 and 5.Homolytic CC-cleavage cannot compete.A concerted β-elimination is the favoured mechanism.
THE ABNORMAL FINKELSTEIN REACTION. A SEQUENTIAL IONIC-FREE RADICAL REACTION MECHANISM
Smith, William B.,Branum, Gary D.
, p. 2055 - 2058 (2007/10/02)
The reaction of alkyl halides with sodium iodide in acetone (Finkelstein Reaction) may yield coupled or rearranged products via cationic intermediates.
