Enantioselective synthesis of 2-(2-hydroxyethyl)allylsilanes from chiral β-hydroxyesters
The synthesis of chiral (2-substituted-2-hydroxyethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition on chiral β-hydroxyesters is described.
Bardot, Valerie,Gelas-Mialhe, Yvonne,Gramain, Jean-Claude,Remuson, Roland