Enantioselective synthesis of 2-(2-hydroxyethyl)allylsilanes from chiral β-hydroxyesters

DOI: 10.1016/S0957-4166(97)00079-7

Source and publish data:

Tetrahedron Asymmetry p. 1111 - 1114 (1997)

Update date:2022-08-10

Topics:

Authors:

Bardot, Valerie

Gelas-Mialhe, Yvonne

Gramain, Jean-Claude

Remuson, Roland

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Article abstract of DOI:10.1016/S0957-4166(97)00079-7

The synthesis of chiral (2-substituted-2-hydroxyethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition on chiral β-hydroxyesters is described.

Full text of DOI:10.1016/S0957-4166(97)00079-7

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Product name:Benzenepropanoic acid, b-[(trimethylsilyl)oxy]-, ethyl ester, (S)-

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