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19352-10-4

2-Methyl-2-phenyloxetane, also known as 2-Methyl-2-phenyloxirane, is a chemical compound with the molecular formula C9H10O. It is an organic compound categorized as an oxetane, which is a cyclic ether with a four-membered ring. 2-methyl-2-phenyloxetane is recognized for its potential applications in medicinal chemistry and the development of new materials, serving as an important intermediate in the synthesis of organic compounds. Its reactive nature necessitates careful handling and use with appropriate safety precautions.

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  • 19352-10-4 Structure

  • Basic information

    1. Product Name: 2-methyl-2-phenyloxetane
    2. Synonyms: 2-methyl-2-phenyloxetane
    3. CAS NO:19352-10-4
    4. Molecular Formula: C10H12O
    5. Molecular Weight: 148
    6. EINECS: N/A
    7. Product Categories: SF190085
    8. Mol File: 19352-10-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: 2-8°C
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-methyl-2-phenyloxetane(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-methyl-2-phenyloxetane(19352-10-4)
    11. EPA Substance Registry System: 2-methyl-2-phenyloxetane(19352-10-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 19352-10-4(Hazardous Substances Data)

19352-10-4 Usage

Uses

Used in Pharmaceutical Industry:
2-Methyl-2-phenyloxetane is used as a building block for the synthesis of various compounds in the pharmaceutical industry. Its unique structure and reactivity make it valuable for creating new drugs and medicinal agents, contributing to advancements in medicinal chemistry.
Used in Chemical Industry:
In the chemical industry, 2-Methyl-2-phenyloxetane is utilized as an intermediate in the synthesis of a range of organic compounds. Its role in creating new materials and its involvement in organic and polymer chemistry highlight its versatility and importance in chemical processes.
Due to its reactive properties, 2-Methyl-2-phenyloxetane should be handled with care to ensure safety in both research and industrial applications.

Check Digit Verification of cas no

The CAS Registry Mumber 19352-10-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,9,3,5 and 2 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 19352-10:
(7*1)+(6*9)+(5*3)+(4*5)+(3*2)+(2*1)+(1*0)=104
104 % 10 = 4
So 19352-10-4 is a valid CAS Registry Number.

19352-10-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-methyl-2-phenyloxetane

1.2 Other means of identification

Product number -
Other names 2-Methyl-2-phenyl-oxetan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:19352-10-4 SDS

19352-10-4Relevant articles and documents

Catalytic Regioselective Isomerization of 2,2-Disubstituted Oxetanes to Homoallylic Alcohols

Cabré, Albert,Lledós, Agustí,Rafael, Sergi,Riera, Antoni,Sciortino, Giuseppe,Ujaque, Gregori,Verdaguer, Xavier

supporting information, p. 7521 - 7527 (2020/03/24)

The selective isomerization of strained heterocyclic compounds is an important tool in organic synthesis. An unprecedented regioselective isomerization of 2,2-disubstituted oxetanes into homoallylic alcohols is described. The use of tris(pentafluorophenyl

Flow microreactor synthesis of 2,2-disubstituted oxetanes via 2-phenyloxetan-2-yl lithium

Degennaro, Leonardo,Nagaki, Aiichiro,Moriwaki, Yuya,Romanazzi, Giuseppe,Dell'anna, Maria Michela,Yoshida, Jun-Ichi,Luisi, Renzo

, p. 377 - 382 (2017/02/10)

A mild and sustainable synthesis of 2,2-disubstituted oxetanes has been achieved through the use of a fow microreactor system. By controlling the residence time a highly unstable intermediate such as 2-phenyloxetan-2-yl lithium can be generated and trappe

Flow microreactor synthesis of 2,2-disubstituted oxetanes via 2-phenyloxetan-2-yl lithium

Degennaro, Leonardo,Nagaki, Aiichiro,Moriwaki, Yuya,Romanazzi, Giuseppe,Del'Anna, Maria Michela,Yoshida, Jun-Ichi,Luisi, Renzo

, p. 377 - 382 (2017/02/26)

A mild and sustainable synthesis of 2,2-disubstituted oxetanes has been achieved through the use of a flow microreactor system. By controlling the residence time a highly unstable intermediate such as 2-phenyloxetan-2-yl lithium can be generated and trapp

Exploiting the lithiation-directing ability of oxetane for the regioselective preparation of functionalized 2-aryloxetane scaffolds under mild conditions

Coppi, Donato Ivan,Salomone, Antonio,Perna, Filippo Maria,Capriati, Vito

supporting information; body text, p. 7532 - 7536 (2012/09/10)

Oxetane nudges in the DoM direction! Regioselective ortho-lithiation induced by an oxetane ring has been achieved. The reaction provides easy access to ortho-functionalized 2-aryloxetanes also through a lithiation/borylation Suzuki-Miyaura cross-coupling. The lithiation-directing ability of oxetane and the proton transfer mechanism have been investigated by competitive metalation and kinetic isotope effect studies. Copyright

2-Lithiated-2-phenyloxetane: A new attractive synthon for the preparation of oxetane derivatives

Coppi, Donato Ivan,Salomone, Antonio,Perna, Filippo Maria,Capriati, Vito

supporting information; experimental part, p. 9918 - 9920 (2011/10/09)

A valuable and direct method to access 2-substituted-2-phenyloxetanes by electrophilic quenching of the corresponding 2-lithiated derivative has, for the first time, been described. 2-Lithiated-2-phenyloxetane was found to be configurationally unstable. E

Reaction of sulfonimidamide Anions with Electrophiles

Okuma, Kentaro,Koike, Tetsufumi,Ohta, Hiroshi

, p. 4190 - 4193 (2007/10/02)

The reaction of alkylsulfonimidamides with bases gave corresponding carboanions, which were allowed to react with carbonyl compounds to give (2-hydroxyalkyl)sulfonimidamides in good yields.When benzoic anhydride or chlorotrimethylsilane was treated with these anions, corresponding phenacylsulfonimidamides or (trimethylsilyl)methylsulfonimidamides were obtained.On the other hand, the reaction of methyl N-p-tosylsulfonimidmorpholide anion with carbonyl compounds afforded epoxides or oxetanes in good yields.

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