213274-31-8Relevant articles and documents
Photocatalyzed Generation of Nitrosocarbonyl Intermediates Under Solar Light Irradiation
Basile, Teresa,Capaldo, Luca,Ravelli, Davide,Quadrelli, Paolo
, p. 1443 - 1447 (2019/06/08)
Tetrabutylammonium decatungstate (TBADT) has emerged as a valuable photocatalyst for sunlight-induced organic reactions. In this communication we wish to present its use for the photocatalytic oxidation of hydroxamic acids to generate fleeting nitrosocarb
Copper-catalyzed aerobic oxidation of N-substituted hydroxylamines: Efficient and practical access to nitroso compounds
Frazier, Charles P.,Bugarin, Alejandro,Engelking, Jarred R.,Read De Alaniz, Javier
experimental part, p. 3620 - 3623 (2012/09/08)
A general and efficient aerobic oxidation of N-substituted hydroxylamines is described. The mild reaction conditions employed provide a catalytic and sustainable alternative to stoichiometric oxidation methods to gain access to a range of nitroso compound
Straightforward hetero Diels-Alder reactions of nitroso dienophiles by microreactor technology
Monbaliu, Jean-Christophe M.R.,Cukalovic, Ana,Marchand-Brynaert, Jacqueline,Stevens, Christian V.
experimental part, p. 5830 - 5833 (2010/12/20)
The hetero Diels-Alder reactions of 2-nitrosotoluene and some representative acylnitrosodienophiles with a selected set of 1,3-dienes were studied under microflow conditions. The main assets of the technology, that is, an accurate control of the reaction
Synthesis of 1,2- and 1,4-amino alcohols from 1,3-dienes via oxazines. Rearrangements of 1,4-amino alcohol derivatives to oxazolines
Werner, Lukas,Hudlicky, Jason Reed,Wernerova, Martina,Hudlicky, Tomas
experimental part, p. 3761 - 3769 (2010/07/05)
Conjugated dienes were converted to 1,2-oxazines by reaction with an acyl nitroso dienophile. The oxazines were reduced to 1,4-N-acetylamino alcohols, which were rearranged to the corresponding oxazolines upon treatment with methanesulfonyl chloride or an
Generation of acyl nitroso compounds by the oxidation of N-acyl hydroxylamines with the Dess-Martin periodinane
Jenkins, Neil E.,Ware Jr., Roy W.,Atkinson, Robert N.,King, S. Bruce
, p. 947 - 953 (2007/10/03)
The oxidation of hydroxamic acids, N-hydroxyureas and N- hydroxycarbamates with the Dess-Martin periodinane generates the corresponding acyl nitroso compounds that react with conjugated dienes to produce the corresponding cycloadducts.
The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses
Quadrelli,Mella,Gamba Invernizzi,Caramella
, p. 10497 - 10510 (2007/10/03)
Nitrile oxides are oxidized by tertiary amine N-oxides in different solvents at room temperature to afford in the presence of dienes nitrosocarbonyl adducts in fair yields. The mild conditions used in oxidizing a variety of nitrile oxides promise a wide application of this method in synthetic processes.
New acylnitroso compounds for the asymmetric oxyamination of dienes
Gouverneur,McCarthy,Mineur,Belotti,Dive,Ghosez
, p. 10537 - 10554 (2007/10/03)
A series of new enantiomerically pure acylnitroso compounds have been prepared and tested as dienophiles for the asymmetric oxyamination of dienes. Very high selectivities were obtained with acylnitroso compounds derived from diphenylmethoxymethyl pyrrolidine 2c, the C2-symmetric pyrrolidines 2d-e and camphorsultam 2f.
A mild oxidation of nitrile oxides: A new synthetic route to nitroso carbonyl intermediates
Quadrelli,Gamba Invernizzi,Caramella
, p. 1909 - 1912 (2007/10/03)
Addition of N-methyl morpholine N-oxide (NMO) to a nitrile oxide solution in dichloromethane at room temperature in the presence of a diene affords nitroso carbonyl adducts in fair yields.
