23732-41-4Relevant articles and documents
A new efficient access to glycono-1,4-lactones by oxidation of unprotected itols by catalytic hydrogen transfer with RhH(PPh3)4-benzalacetone system
Isaac,Aizel,Stasik,Wadouachi,Beaupère
, p. 475 - 476 (2007/10/03)
Treatment of unprotected pentitols and hexitols with RhH(PPh3)4-benzalacetone system leads exclusively to glycono-1,4-lactones in 60-96% yield.
Autoxidation Reaction Mechanism for L-Ascorbic Acid-related Compounds in Methanol without Metal Ion Catalysis
Miyake, Noriko,Kurata, Tadao
, p. 811 - 813 (2007/10/03)
The autoxidation mechanism for L-ascorbic acid (ASA)-related compounds such as D-arabo-ascorbic acid (= erythorbic acid; ERA) and triose reductone (TR) in methanol without metal ion catalysis was studied.The oxidation reaction of these ASA-related compounds seems to proceed via the C(2) oxygen adduct of ERA (or TR) by a similar reaction mechanism to that of ASA. - Keywords: L-ascorbic acid; autoxidation; D-erythorbic acid; triose reductone; C(2) oxygen adduct