cas 251647-48-0, N-Benzoyl-5'-O-[bis(4-methoxyphenyl)phenylmethyl]-2'-O-(2-methoxyethyl)adenosine

Articles about 251647-48-0Total 3 be found

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Copper(II)nitrate catalyzed regioselective protection of primary alcohols with 4,4′-dimethoxytrityl and 2,7-dimethyl-9-phenyl xanthen-9-yl groups in nucleosides and carbohydrates
Regioselective protection of primary hydroxyl group in nucleoside and carbohydrate analogs was accomplished using dimethoxytrityl alcohol (DMTr-OH) or dimethylpixyl alcohol (DMPx-OH) in presence of copper(II)nitrate as a Lewis acid catalyst. Excellent selectivity was observed for the protection of primary hydroxyl group over secondary while glycosidic bond remain unaffected. Utility of this methodology was further exemplified via DMTr- and DMPx-protection of alipahtic acyclic and cyclic diols.
Penjarla, Srishylam,Prasad, S. Rajendra,Reddy, Dhande Sudhakar,Banerjee, Shyamapada,Penta, Santhosh,Sanghvi, Yogesh S.
p. 232 - 247
(2018/05/14)

Synthesis and cellular activity of stereochemically-pure 2′-O-(2-methoxyethyl)-phosphorothioate oligonucleotides
Stereochemically-pure 2′-O-(2-methoxyethyl)-phosphorothioate (PS-MOE) oligonucleotides were synthesized from new chiral oxazaphospholidine-containing nucleosides. Thermal stability studies showed that the incorporation of Rp-PS linkages increased RNA-binding affinity. In cells, a full Rp-PS-MOE splice-switching oligonucleotide targeting part of the ferrochelatase gene was more potent than its Sp-PS counterpart, but of similar potency to the stereorandom PS-parent sequence.
Li,Lightfoot,Halloy,Malinowska,Berk,Behera,Schümperli,Hall
p. 541 - 544
(2017/01/13)

2'-O-MOE-3'-H-phosphorothioate nucleoside monomer and synthetic method thereof
The invention discloses 2'-O-MOE-3'-H-phosphorodithioate ribonucleotide and 2'-O-MOE-3'-H-phosphorothioate ribonucleotide and precursor compounds thereof, preparation methods and applications of the 2'-O-MOE-3'-H-phosphorodithioate ribonucleotide and the
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(2017/01/23)

Chemical Properties

Density: 1.31
Solubility:Acetonitrile (Sparingly), Chloroform (Slightly), DMF (Slightly, Sonicated), DMSP
Storage Temp.:2-8°C
PKA: 7.87±0.43(Predicted)
PSA: 151.80000
LogP: 5.77840

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251647-48-0

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Chemical Properties

Density: 1.31

Solubility:Acetonitrile (Sparingly), Chloroform (Slightly), DMF (Slightly, Sonicated), DMSP

Storage Temp.:2-8°C

PKA: 7.87±0.43(Predicted)

PSA: 151.80000

LogP: 5.77840

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