26042-63-7

Basic information

• Product Name: Silver hexafluorophosphate
• Synonyms: SILVER(I)HEXAFLUOROPHOSPHATE;SILVER HEXAFLUOROPHOSPHATE;SILVER HEXAFLUOROPHOSPHATE (V);hexafluoro-phosphate(1-silver(1++);SILVER HEXAFLUOROPHOSPHATE, 99.99%;Silver(I) hexafluorophosphate(V);Silver hexafluorophosphate, 98%, -6 mesh;Silverhexafluorophosphate,99%
• CAS NO: 26042-63-7
• Molecular Formula: Ag*F₆P
• Molecular Weight: 252.83
• EINECS: 247-428-6
• Product Categories: Gold Catalysis;Silver AdditivesMetal and Ceramic Science;SilverCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Chemical Synthesis;Salts;Silver Salts;SilverMetal and Ceramic Science;metal fluorophosphate complex;Silver Additives;Catalysis and Inorganic Chemistry;Chemical Synthesis;Gold Catalysis;Materials Science;Metal and Ceramic Science;Silver;Silver Salts
• Mol File: 26042-63-7.mol

Chemical Properties

• Melting Point: 102 °C (dec.)(lit.)
• Appearance: Yellow to pale brown/Powder
• Solubility: Soluble in organic solvents such as benzene, toluene, and aceton
• Water Solubility: soluble
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: Silver hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: Silver hexafluorophosphate(26042-63-7)
• EPA Substance Registry System: Silver hexafluorophosphate(26042-63-7)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45-36/39
• RIDADR: UN 3260 8/PG 2
• WGK Germany: 3
• F: 1-3-8-9
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 26042-63-7(Hazardous Substances Data)

Usage

Uses

Used in Gold Catalysts:
Silver hexafluorophosphate is used as a catalyst in the 21st-century "Gold Rush," where it plays a crucial role in the development of new catalysts, particularly in the replacement of halide ligands with the weakly coordinating hexafluorophosphate anion.
Used in Oxidation Processes:
It is commonly used as an oxidant for forming silver metal, which is essential in various chemical reactions and applications.
Used in Inorganic and Organometallic Chemistry:
Silver hexafluorophosphate is used as a reagent in inorganic and organometallic chemistry, where its unique properties contribute to the advancement of research and development in these fields.
Used in Material Science:
It is employed in the preparation of novel engineering materials, which can have a wide range of applications in various industries, from electronics to construction.
Used in Supramolecular Chemistry:
Silver hexafluorophosphate is used in the preparation of supra molecular Ag(I) complexes, which are essential in the study and development of supramolecular chemistry and its applications.
Used in Catalyst Development:
It is utilized in the development of new catalysts, where its unique properties allow for the creation of more efficient and environmentally friendly catalysts for various chemical processes.

InChI:InChI=1/12Ag.6FH2O3P/c;;;;;;;;;;;;6*1-5(2,3)4/h;;;;;;;;;;;;6*(H2,2,3,4)/q12*+1;;;;;;/p-12

Upstream product

• 7726-95-6 bromine 
• 7440-22-4 silver 
• 11113-87-4 silver fluoride 
• 7647-19-0 phosphorus pentafluoride 
• 7647-19-0 phosphorus pentafluoride 
• 17084-13-8 potassium hexafluorophosphate 
• 3109-63-5 tert-butylammonium hexafluorophosphate(V) 
• 7783-55-3 trifluorophosphane 

Downstream Products

• 13478-20-1 trifluorophosphoric acid 
• 95464-87-2 silver difluorophosphinato 
• 118206-92-1 cis-{Pt(PPh₃)2(dmso)2}(PF₆)2 
• 113706-08-4 {iridium(1,3-bis(diphenylphosphino)propane)2}PF₆ 
• 101307-69-1 {Rh(C8H12)(η6-(C6H5)2CO)}PF6 
• 64668-07-1 Au(S(CH₃)2)(P(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=[Au(S(CH₃)2)(P(C₆H₅)3)]PF₆ 
• 64668-11-7 Au(C₅H₁₀NH)(P(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=[Au(C₅H₁₀NH)(P(C₆H₅)3)]PF₆ 
• 78897-25-3 (C₅H₅)Fe(CO)2(OCHC₆H₅)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Fe(CO)2(OCHC₆H₅)]PF₆ 
• 212051-60-0 [RuH(η(6)-C6H6)(AsPh3)2]PF6 
• 212051-62-2 [RuH(η(6)-C6H6)(SbPh3)2]PF6 

Relevant articles and documents

Synthesis and characterization of luminescent zinc(II) complexes with a N,N-bidentate 1-pyridylimidazo[1,5-a]pyridine ligand

Ligand 2-(1-(pyridin-2-yl)imidazo[1,5-a]pyridin-3-yl)phenol (L) has been reacted in a 2:1 molar ratio with different Zn(Y)2nH2O salts, where Y represents a polyatomic anion (Y = ClO4-, NO3-, BF4-, PF6-). The X-ray structural analysis performed on two of the derivatives obtained, namely [Zn(L)2(ClO4)](ClO4)·H2O (1) and [Zn(L)2(CH3CN)2](BF4)2 (6), proves that as expected ligand L binds in a N,N-bidentate mode via the pyridine ring (Npy) and the pyridine-like nitrogen of the imidazo[1,5-a]pyridine skeleton (Nim). A spectroscopic investigation (including infrared, elemental analysis, 1H and 31P NMR, thermogravimetric analysis) has been performed on these species, allowing complete characterizations. A preliminary survey on their photophysical properties in the solid state was carried out: the complexes showing intense luminescence when excited with UV light (λexc = 421-469 nm) with λmax of emission in the blue-green range (468-500 nm) and moderate absolute photoluminescence quantum yields (PLQYs).

Difluorobis(pentafluoroethyl)phosphoranide: A Promising Building Block for Phosphoranidometal Complexes

Despite the fact that different metal tetrafluorophosphoranides, M[PF4] (M = Cs, Ag, K), decompose readily, we successfully enhanced the stability of such species by the replacement of two fluorine atoms with electron withdrawing pentafluoroethyl groups. Thus, AgF adds to P(C2F5)2F, yielding Ag[P(C2F5)2F2], which served as a starting material for the synthesis of mono-, bis-, and tris[difluorobis(pentafluoroethyl)phosphoranido]silver complexes. Addition of 2,2′-bipyridine allowed for the isolation of stable [Ag(bipy){P(C2F5)2F2}], whereas the reaction with the chlorides [NMe4]Cl and CoCl2 afforded the bis- and trisphosphoranidoargentates [NMe4][Ag{P(C2F5)2F2}2(OEt2)] and [Co(NCMe)6][Ag{P(C2F5)2F2}3]·2MeCN, respectively. Altogether, the difluorobis(pentafluoroethyl)phosphoranido moiety serves as a novel, small, noncyclic phosphoranido ligand. It provided access to the first homoleptic phosphoranidometal complex, [Co(NCMe)6][Ag{P(C2F5)2F2}3]·2MeCN, which itself features the unusual structural motif of an [AgX3]2- ion.

MANUFACTURING METHOD OF FLUORINATED HYDROCARBON

PROBLEM TO BE SOLVED: To provide a method for industrially advantageously manufacturing fluorinated hydrocarbon (3). SOLUTION: There is provided a method for manufacturing fluorinated hydrocarbon represented by the formula (3), including contacting a secondary or tertiary ether compound represented by the formula (1) and acid fluoride represented by the formula (2) in the presence of a silver salt in a hydrocarbon solvent. R1 and R2 are each independently a C1 to 3 alkyl group, R1 and R2 may bind to form a ring structure, R3 is H, a methyl group or an ethyl group, R4 and R5 are each independently a methyl group or an ethyl group. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT