272451-69-1

Basic information

• Product Name: N~1~-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-N~2~-[2-methyl-1-(methylsulfinyl)propan-2-yl]benzene-1,2-dicarboxamide
• Synonyms: 1,2-benzenedicarboxamide, N~2~-[1,1-dimethyl-2-(methylsulfinyl)ethyl]-3-iodo-N~1~-[2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-; N~1~-[4-(1,1,1,2,3,3,3-Heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-N~2~-[2-methyl-1-(methylsulfinyl)propan-2-yl]phthalamide
• CAS NO: 272451-69-1
• Molecular Formula: C₂₃H₂₂F₇IN₂O₃S
• Molecular Weight: 666.3907
• Mol File: 272451-69-1.mol

Chemical Properties

• Boiling Point: 567.618°C at 760 mmHg
• Flash Point: 297.085°C
• Density: 1.621g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.568
• CAS DataBase Reference: N~1~-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-N~2~-[2-methyl-1-(methylsulfinyl)propan-2-yl]benzene-1,2-dicarboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N~1~-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-N~2~-[2-methyl-1-(methylsulfinyl)propan-2-yl]benzene-1,2-dicarboxamide(272451-69-1)
• EPA Substance Registry System: N~1~-[4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-2-methylphenyl]-3-iodo-N~2~-[2-methyl-1-(methylsulfinyl)propan-2-yl]benzene-1,2-dicarboxamide(272451-69-1)

Safety Data

• Hazardous Substances Data: 272451-69-1(Hazardous Substances Data)

Upstream product

• 36567-04-1 2-methyl-1-methylthio-2-propylamine 
• 28418-88-4 3-iodophthalic anhydride 
• 150884-56-3 N-tert-butyloxycarbonyl-3-(4-cyanophenyl)oxaziridine 
• 371771-07-2 N-(2-methyl-4-heptafluoroisopropylphenyl)-N₂-(1,1-dimethyl-2-methylsulfonylethyl)-(1,2-benzene formamide) 
• 2232-12-4 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione 
• 866639-19-2 3-iodo-N-(1,1-dimethyl-2-methylthioethyl)-o-carbamoylbenzoic acid 

Downstream Products

• 272451-65-7 flubendiamide 

Relevant articles and documents

Palladium/carbon catalytic aromatic functional group on the adjacent position iodizate method

The invention discloses a method for iodization of an ortho-position of a functional group on a palladium/carbon catalytic aromatic ring. The method comprises the following steps: mixing an aromatic ring of which a substrate contains a functional group, a

Novel diamide insecticides: Sulfoximines, sulfonimidamides and other new sulfonimidoyl derivatives

Novel insecticidal anthranilamides with elaborated sulfur-containing groups are described. The synthesis of compounds with functional groups such as sulfoximines and scarcely reported groups such as sulfonimidoyl hydrazides and hydroxylamides, their in vitro and in vivo biological activity as well as their physical properties are reported.

PROCESS FOR PRODUCING 2-HALOGENOBENZAMIDE COMPOUND

A novel process for producing a 2-halogenobenzamide compound useful as a raw material or active ingredient for medicines and agricultural chemicals. The process, which is for producing a 2-halogenobenzamide compound represented by the general formula (I): (wherein R1, R2, R3, R4, and R6 may be the same or different and each represents hydrogen or C1-6 alkyl; R5 represents C1-6 alkyl; k is 1 or 2; Y1, Y2, Y3, and Y4 may be the same or different and each represents hydrogen, halogeno, etc.; and X represents chlorine, bromine, or iodine), is characterized by reacting an benzamide compound with a halogenating agent in the presence of a palladium catalyst to obtain a substituted benzamide compound and then reacting the resultant substituted benzamide compound with an oxidizing agent after or without isolating the substituted benzamide compound.

Process for the preparation of 2-halobenzoic acids

The present invention provides a process for producing 2-halobenzoic acids of the general formula (I), characterized by reacting a benzoic acid of formula (II) with a halogenating agent in the presence of Pd catalyst: (wherein A is —OH, —OM (M is alkali metal), —N(R6)R7 (R6 and R7 are each H, C1-C6 alkyl, optionally substituted phenyl, or the like) ; R is H, C1-C6 alkyl, C1-C6 alkylcarbonyl, carboxyl, C1-C12 alkoxycarbonyl, optionally substituted phenylcarbonyl, or the like; n is 0 to 4; X is Cl, Br or I, or alternatively (R)n may be present on benzene-constituting carbon atoms adjacent to each other and form a C3-C4 alkylene- or C3-C4 alkenylene-fused ring).