284049-37-2

Basic information

• Product Name: 1H-Pyrrole,2-ethenyl-1-(2-propenyl)-(9CI)
• Synonyms: 1H-Pyrrole,2-ethenyl-1-(2-propenyl)-(9CI)
• CAS NO: 284049-37-2
• Molecular Formula: C9H11N
• Molecular Weight: 133.19034
• Product Categories: AMINETERTIARY
• Mol File: 284049-37-2.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Pyrrole,2-ethenyl-1-(2-propenyl)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Pyrrole,2-ethenyl-1-(2-propenyl)-(9CI)(284049-37-2)
• EPA Substance Registry System: 1H-Pyrrole,2-ethenyl-1-(2-propenyl)-(9CI)(284049-37-2)

Safety Data

• Hazardous Substances Data: 284049-37-2(Hazardous Substances Data)

Upstream product

• 1779-49-3 Methyltriphenylphosphonium bromide 
• 101001-68-7 1-allyl-1H-pyrrole-2-carbaldehyde 
• 1003-29-8 2-pyrrole aldehyde 

Downstream Products

• 1432755-04-8 ((1R,2R,4S)-2-(1-allyl-1H-pyrrol-2-yl)-4-phenylcyclobutyl)methanol 
• 1432755-11-7 ((1R,2R,4S)-2-(1-allyl-1H-pyrrol-2-yl)-4-(4-bromophenyl)cyclobutyl)methano 
• 1432755-23-1 ((1R,2R,4S)-2-(1-allyl-1H-pyrrol-2-yl)-4-phenylcyclobutyl)methyl pent-4-enoate 
• 1432755-24-2 (2S,2aR,14bR,E)-2-phenyl-2a,3,6,7,10,14b-hexahydro-1H-cyclobuta[c]pyrrolo[2,1-e][1,6]oxaazacyclododecin-5(2H)-one 
• 1432755-05-9 ((1R,2R,4S)-2-(1-allyl-1H-pyrrol-2-yl)-4-(o-tolyl)cyclobutyl)methanol 
• 1432755-25-3 C₁₈H₁₈BrNO 
• 1432755-13-9 4-((1S,2R,3R)-3-(1-allyl-1H-pyrrol-2-yl)-2-(hydroxymethyl)cyclobutyl)benzonitrile 
• 1432755-14-0 ((1R,2R,4S)-2-(1-allyl-1H-pyrrol-2-yl)-4-(4-(trifluoromethyl)phenyl)cyclobutyl)methanol 

Relevant articles and documents

Organocatalytic formal [2+2] cycloaddition initiated by vinylogous Friedel-Crafts alkylation: Enantioselective synthesis of substituted cyclobutane derivatives

An organocatalytic vinylogous Friedel-Crafts alkylation-initiated formal [2+2] cycloaddition was successfully developed based on tandem iminium-enamine activation of enals. Transformable pyrrole-functionalized cyclobutanes with three contiguous stereocenters were readily obtained with excellent levels of regio-, diastereo- and enantiocontrol. The Royal Society of Chemistry 2013.

Organoyttrium-catalyzed sequential cyclization/silylation reactions of nitrogen-heteroaromatic dienes demonstrating 'aryl-directed' regioselectivity

The reaction of 1-allyl-2-vinyl-1H-pyrroles and 1-allyl-2-vinyl-1H- indoles with arylsilanes in the presence of catalytic [Cp(TMS)2Y(μ-Me)]2 leads to highly selective cyclization/silylation events. In this process the active catalyst for the reaction, 'Cp(TMS)2YH', undergoes initial olefin insertion at the vinyl group. Even isopropenyl substituents on the heteroaromatics react in preference to less sterically encumbered allyl groups. Furthermore, the observed regioselectivity reflects an 'aryl- directed' process, whereby the more highly substituted secondary or tertiary organometallic is initially generated. This intermediate undergoes cyclization onto the remaining alkene and subsequent silylation by a σ-bond metathesis reaction, affording the observed products.