302338-13-2

Basic information

• Product Name: Cyclopentanecarboxaldehyde, 2,2-dimethyl-1-(2-nitroethyl)-, (1S)- (9CI)
• Synonyms: Cyclopentanecarboxaldehyde, 2,2-dimethyl-1-(2-nitroethyl)-, (1S)- (9CI)
• CAS NO: 302338-13-2
• Molecular Formula: C10H17NO3
• Molecular Weight: 199.24688
• Product Categories: CYCLOPENTANE
• Mol File: 302338-13-2.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopentanecarboxaldehyde, 2,2-dimethyl-1-(2-nitroethyl)-, (1S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentanecarboxaldehyde, 2,2-dimethyl-1-(2-nitroethyl)-, (1S)- (9CI)(302338-13-2)
• EPA Substance Registry System: Cyclopentanecarboxaldehyde, 2,2-dimethyl-1-(2-nitroethyl)-, (1S)- (9CI)(302338-13-2)

Safety Data

• Hazardous Substances Data: 302338-13-2(Hazardous Substances Data)

Upstream product

• 70030-18-1 2,2-dimethylcyclopentanecarboxaldehyde 
• 18942-89-7 2-nitroethyl acetate 
• 325705-63-3 (S)-1-[2,2-Dimethyl-cyclopent-(E)-ylidenemethyl]-2-methoxymethyl-pyrrolidine 

Downstream Products

• 55811-47-7 (5S)-(+)-6,6-dimethyl-2-azaspiro[4.4]non-1-ene 

Relevant articles and documents

Enantioselective synthesis of polyzonimine and nitropolyzonamine, spirocyclic compounds from the defensive glands of a millipede, Polyzonium rosalbum

Asymmetric Michael addition of the enamine derived from 2,2-dimethylcyclopentanecarboxaldehyde and (S)-prolinol methyl ether to nitroethylene afforded the adduct of 76% ee, which finally yielded enantiomerically pure (+)-polyzonimine and (+)-nitropolyzonamine, compounds from the defensive glands of a millipede, Polyzonium rosalbum. The absolute configuration of (+)-polyzonimine was determined as S. (C) 2000 Elsevier Science Ltd.