32221-81-1Relevant articles and documents
CATALYTIC POTENCY OF FUNCTIONALIZED (2,5)PYRIDINOPHANES AS NEW PYRIDOXAL MODEL COMPOUNDS
Iwata, Masaaki,Kuzuhara, Hiroyoshi
, p. 5 - 6 (1981)
Catalytic activities of new model compounds, 1a-c, 2, and 3, for the racemization of monosodium L-glutamate were shown to be more potent, ca. 1.5 fold, than that of pyridoxal, and catalyst, 1a, was stable enough to show no decomposition throughout the reaction.
CAGED COMPOUND, AND MANUFACTURING METHOD AND EXPRESSION METHOD OF CAGED COMPOUND
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Paragraph 0166; 0167, (2019/03/01)
PROBLEM TO BE SOLVED: To provide a caged compound excellent in light reactivity and dark place stability, and capable of deprotection by a visible light. SOLUTION: A caged compound is represented by the following general formula (1). In the general formula (1), R1 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cyano group, an alkoxy group, a hydroxy group, or an alkylamino group, R2 represents an alkyl group or a hetero atom other than a nitrogen atom, R3 represents a hydrogen atom, a halogen atom or an alkyl group, X represents a monovalent anion, Y represents a monovalent organic group, Z represents a hydrogen atom or a monovalent organic group, and a represents 0 or 1, however a represents 0 when R2 represents the hetero atom other than the nitrogen atom. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT
Silicon nanowire photocathodes for light-driven electroenzymatic synthesis
Lee, Sahng Ha,Ryu, Gyeong Min,Nam, Dong Heon,Kim, Jae Hong,Park, Chan Beum
, p. 3007 - 3011 (2015/09/28)
The photoelectroenzymatic synthesis of chemical compounds employing platinum nanoparticle-decorated silicon nanowires (Pt-SiNWs) is presented. The Pt-SiNWs proved to be an efficient material for photoelectrochemical cofactor regeneration because the silicon nanowires absorbs a wide range of the solar spectrum while the platinum nanoparticle serve as an excellent catalyst for electron and proton transfer. By integrating the platform with redox enzymatic reaction, visible-light-driven electroenzymatic synthesis of L-glutamate was achieved. Compared to electrochemical and photochemical methods, this approach is free from side reactions caused by sacrificial electron donors and has the advantage of applying low potential to realize energy-efficient and sustainable synthesis of chemicals by a photoelectroenzymatic system.
Process for chemical reaction of amino acids and amides yielding selective conversion products
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Page 7-8, (2008/06/13)
The invention relates to processes for converting amino acids and amides to desirable conversion products including pyrrolidines, pyrrolidinones, and other N-substituted products. L-glutamic acid and L-pyroglutamic acid provide general reaction pathways to numerous and valuable selective conversion products with varied potential industrial uses.