33510-35-9Relevant articles and documents
Design and synthesis of extended π-systems: Monomers, oligomers, polymers
Scherf,Mullen
, p. 23 - 38 (2007/10/02)
The synthesis of unconventional extended π-systems is described in an attempt to tailor the structures of organic compounds for specific optical and electrical properties. In order to emphasize the role of the π-conjugation and to correlate chemical structure and physical function both one-dimensional arylenevinylenes and two-dimensional ribbon-type molecules are considered. In the synthesis of the former the aryl-olefin coupling according to Heck is of special value, the synthesis of the latter is achieved by repetitive Diels-Alder cycloadditions and by two-step processes in which carefully designed polyaryl precursors are subjected to ring closure. Key ingredients of the present approach are the interplay of synthetic organic chemistry and synthetic macromolecular chemistry and the needs outlined by materials sciences. Thereby, transition from monomers to oligomers and polymers defines new requirements for the selectivity of the synthetic reactions and the tractability of the products.
ORIENTATION SELECTIVE BOND CLEAVAGE REACTIONS OF BIPHENYL-FUSED 1,2-DIPHENYLCYCLOBUTANES INITIATED BY ELECTRON TRANSFER1
Yamashita, Yoshiro,Yaegashi, Hisao,Mukai, Toshio
, p. 3579 - 3582 (2007/10/02)
Biphenyl-fused 1,2-diphenylcyclobutanes underwent orientation selective bond cleavage in the photosensitized reactions using DCA as a sensitizer or aminium cation radical catalyzed reactions.