34155-83-4Relevant articles and documents
Acylation of 2,2-Dimathyl-2H-chromenes
Yamaguchi, Seiji,Yamamoto, Satoru,Abe, Shoichi,Kawase, Yoshiyuki
, p. 442 - 445 (2007/10/02)
Orientation in acylation reactions of 2,2-dimethyl-2H-chromenes was studied.Five acetylchromenes were obtained with two methods and six formylchromenes were obtained with a third method.Demethylation of four acyl-methoxy-substituted chromenes gave the corresponding acylchromenols. 2,2-Dimethyl-2H-chromene-6-carboxylic acid (anofinic acid) was also obtained by oxidation of 6-formylchromene.
A New Synthesis of Some Naturally Occurring Acetylchromenes
Ahluwalia, V. K.,Arora, K. K.,Manchanda, Saroj
, p. 1039 - 1040 (2007/10/02)
Acetovanillochromene (1) has been synthesized by the nuclear isoprenylation of 4-hydroxy-3-methoxyacetophenone (4) followed by dehydrogenation of the chromane (5), thus formed.Similarly, 6-acetyl-5-hydroxy-8-methoxy-2,2-dimethyl-2H-1-benzopyran (2) and its methyl ether (3) have also been synthesized.All the three chromenes (1 - 3) are naturally occurring.