35630-06-9

Basic information

• Product Name: trans-1,2-cyclobutanedimethanol, bis(toluenesulfonate)
• CAS NO: 35630-06-9
• Molecular Weight: 424.539
• Mol File: 35630-06-9.mol

Chemical Properties

• CAS DataBase Reference: trans-1,2-cyclobutanedimethanol, bis(toluenesulfonate)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1,2-cyclobutanedimethanol, bis(toluenesulfonate)(35630-06-9)
• EPA Substance Registry System: trans-1,2-cyclobutanedimethanol, bis(toluenesulfonate)(35630-06-9)

Safety Data

• Hazardous Substances Data: 35630-06-9(Hazardous Substances Data)

Upstream product

• 7371-67-7 dimethyl trans-1,2-cyclobutane dicarboxylate 
• 7371-64-4 trans-(cyclobutane-1,2-diyl)dimethanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 2607-03-6 dimethyl cis-1,2-cyclobutanedicarboxylate 
• 412346-70-4 1-cyano-cyclobutane-1,2-dicarboxylic acid diethyl ester 
• 869-10-3 diethyl 2,5-dibromoadipate 

Relevant articles and documents

Understanding the Structure–Polymerization Thermodynamics Relationships of Fused-Ring Cyclooctenes for Developing Chemically Recyclable Polymers

Polymers that can be chemically recycled to their constituent monomers offer a promising solution to address the challenges in plastics sustainability through a circular use of materials. The design and development of monomers for next-generation chemical

A Stereochemical Study of the Thermolysis of cis-anti- and trans-1,2-Dimethyl-cis-3,4-dideuteriocyclobutane

The stereochemistry of the fragmentation and isomerization of cis-anti- and trans-1,2-dimethyl-cis-3,4-dideuteriocyclobutane at 510 deg C is reported.The cis-anti-cis isomer undergoes fragmentation to yield cis/trans-propene-d1 (1.5/1, major pathway), cis/trans-2-butene (1.4/1), and cis/trans-ethylene-d2 (1/1, minor pathway).Recovered cis-1,2-dimethylcyclobutane-d2 containing approximately 40percent of the double rotation product relative to the product of single methyl rotation, trans-1,2-dimethylcyclobutane-d2.The trans isomer behaves similarly, yielding cis/trans-propene-d1 (1/1, major pathway), cis/trans-2-butene (1/5), and cis/trans-ethylene-d2 (1/1, minor pathway).Recovered cis-1,2-dimethylcyclobutane-d2 from thermolysis of the trans isomer consists mainly of equal amounts of cis-anti-cis- and cis-syn-cis-1m2-dimethylcyclobutane-d2 as analyzed by NMR.On the basis of product composition, the thermal chemistry of this system can be explained as proceeding through 2,5-hexanediyl (major pathway) and 3-methyl-1,4-pentanediyl (minor pathway).On the basis of the observed stereochemistry, it can be concluded that the lifetimes of both 2,5-hexanediyl and 3-methyl-1,4-pentanediyl are similar and of the same order as bond rotations at a radical center.This suggests that the gauche to trans conformational changes involving carbon-carbon bond rotation at carbon 2 and 3 of 1,4-diyls may not be competitive with fragmentation.