380626-41-5

Basic information

• Product Name: tert-butyl tricyclo[8.2.2.2~4,7~]hexadeca-1(12),4,6,10,13,15-hexaen-5-ylcarbamate
• Synonyms: tert-butyl tricyclo[8.2.2.2~4,7~]hexadeca-1(12),4,6,10,13,15-hexaen-5-ylcarbamate
• CAS NO: 380626-41-5
• Molecular Formula: C₂₁H₂₅NO₂
• Molecular Weight: 323.4287
• Mol File: 380626-41-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: tert-butyl tricyclo[8.2.2.2~4,7~]hexadeca-1(12),4,6,10,13,15-hexaen-5-ylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl tricyclo[8.2.2.2~4,7~]hexadeca-1(12),4,6,10,13,15-hexaen-5-ylcarbamate(380626-41-5)
• EPA Substance Registry System: tert-butyl tricyclo[8.2.2.2~4,7~]hexadeca-1(12),4,6,10,13,15-hexaen-5-ylcarbamate(380626-41-5)

Safety Data

• Hazardous Substances Data: 380626-41-5(Hazardous Substances Data)

Upstream product

• 26456-39-3 Tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4,6,10⁽¹⁴⁾,11,15-hexaene-5-carbonyl azide 
• 75-65-0 tert-butyl alcohol 
• 4248-19-5 tert-butyl carbazate 
• 1908-61-8 4-bromo[2.2]paracyclophane 

Downstream Products

• 196086-92-7 (±)-4-benzylamino[2.2]paracyclophane 
• 200504-30-9 N-Benzyl-3-phenyl-N-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4,6,10⁽¹⁴⁾,11,15-hexaen-5-yl-propionamide 
• 200504-32-1 N-Benzyl-2-phenyl-N-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4,6,10⁽¹⁴⁾,11,15-hexaen-5-yl-acetamide 
• 200504-27-4 N-Benzyl-N-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4,6,10⁽¹⁴⁾,11,15-hexaen-5-yl-propionamide 

Relevant articles and documents

Phenyliodine diacetate-mediated para-functionalizations of amido- and amino-substituted [2.2]paracyclophanes

The reaction of N-[2.2]paracyclophanyl-substituted amides or amines with phenyliodine diacetate (PIDA) and protic nucleophiles affords mixed para-substituted [2.2]paracyclophane derivatives in moderate to good yields. As protic nucleophiles carboxylic aci

N-Methyl- and N-benzyl-4-amino[2.2]paracyclophanes as unique planar chiral auxiliaries

Efficient production of racemic and homochiral N-alkyl-[2.2]paracyclophanes from [2.2]paracyclophane via racemic and homochiral 4-carboxy [2.2]paracyclophane is described, including an excellent procedure for the synthesis of homochiral 4-amino[2.2]paracyclophane. Enolisation followed by electrophilic attack proceeds with diastereoselectivities varying from excellent to modest and the chiral auxiliaries are readily recovered in good yields; the configurational stability of the α-haloamides produced is examined.