38365-55-8

Basic information

• Product Name: Benzene, 1-broMo-4-(2,2-dichlorocyclopropyl)-
• Synonyms: Benzene, 1-broMo-4-(2,2-dichlorocyclopropyl)-;1-bromo-4-(2,2-dichlorocyclopropyl)benzene
• CAS NO: 38365-55-8
• Molecular Formula: C₉H₇BrCl₂
• Molecular Weight: 265.96188
• Mol File: 38365-55-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1-broMo-4-(2,2-dichlorocyclopropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-broMo-4-(2,2-dichlorocyclopropyl)-(38365-55-8)
• EPA Substance Registry System: Benzene, 1-broMo-4-(2,2-dichlorocyclopropyl)-(38365-55-8)

Safety Data

• Hazardous Substances Data: 38365-55-8(Hazardous Substances Data)

Upstream product

• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 67-66-3 chloroform 
• 2415-80-7 1,1-dichloro-2-phenylcyclopropane 

Downstream Products

• 192432-78-3 3-(4-bromophenyl)-5-chloroisoxazole 
• 1200-07-3 3-(4-bromophenyl)acrylic acid 
• 1427282-27-6 1-(4-bromophenyl)-3,3-dichloroprop-2-en-1-one oxime 
• 1427282-28-7 3-(4-bromophenyl)-1,1,5,5-tetrachloropenta-1,4-diene 

Relevant articles and documents

Acid-catalyzed cleavage of C-C bonds enables atropaldehyde acetals as masked C2 electrophiles for organic synthesis

Acid-catalyzed tandem reactions of atropaldehyde acetals were established for the synthesis of three important molecules, 2,2-disubstituted indolin-3-ones, naphthofurans and stilbenes. The synthesis was realized using novel reaction cascades, which involved the same two initial steps: (i) SN2′ substitution, in which the atropaldehyde acted as an electrophile; and (ii) oxidative cleavage of the carbon-carbon bond of the generated phenylacetaldehyde-type products. Compared with literature methods, the present protocol not only avoided the use of expensive noble metal catalysts, but also enabled a simple operation.

Spectroscopic analysis of the products of the cycloaddition reaction of 1-Aryl-2-chlorocyclopropenes and cyclopentadiene

The treatment of a series of 1-aryl-2,2-dihalocyclopropanes with t-BuOK at -10 °C produces the corresponding 1-aryl-2-halocyclopropenes, which react with cyclopentadiene to produce fairly good yield of [4+2]-cycloaddition products with more than 90% of the endo-isomer. The higher yield obtained from hexane medium then from methanol and ionic liquid demonstrates that the reaction is a nonpolar process. The treatment of a series of 1-aryl-2,2- dihalocyclopropanes with t-BuOK at -10 °C produces the corresponding 1-aryl-2-halocyclopropenes, which react with cyclopentadiene to produce fairly good yield of [4+2]-cycloaddition products with more than 90% of the endo-isomer. The higher yield obtained from hexane medium then from methanol and ionic liquid demonstrates that the reaction is a nonpolar process. Copyright

Ionic liquids accelerating cycloaddition between 1-aryl-2-halocyclopropenes and furan

Treatment of a series of 1-aryl-2,2-dihalocyclopropanes with t-BuOK at-10 °C gave the corresponding 1-aryl-2-halocyclopropenes, which react with furan in a RTIL to give a fair good yield of the [4+2]-cycloadducts with more than 90% of the exo-isomer. The imidazolium type ionic liquids are able to accelerate this cycloaddition process with high steric selectivity. Neither pyrrole nor thiophene undergoes the cycloaddition with cyclopropene to form the [4+2]-cycloadduct. 1-Aryl-3,3-difluoro-2-halocyclopropenes are inert towards furan even at a temperature higher than 100 °C.