425629-22-7

Basic information

• Product Name: 2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine
• Synonyms: 2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine
• CAS NO: 425629-22-7
• Molecular Formula: C₂₇H₁₅N₃
• Molecular Weight: 381.43
• Mol File: 425629-22-7.mol

Chemical Properties

• Boiling Point: 593.6±60.0 °C(Predicted)
• Appearance: /
• Density: 1.28±0.1 g/cm3(Predicted)
• PKA: 0.02±0.10(Predicted)
• CAS DataBase Reference: 2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine(425629-22-7)
• EPA Substance Registry System: 2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine(425629-22-7)

Safety Data

• Hazardous Substances Data: 425629-22-7(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Research:
2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine is used as a research compound for its potential applications in the development of new pharmaceuticals. Its unique structure and reactivity make it a candidate for exploring novel drug interactions and mechanisms.
Used in Advanced Material Science:
In the field of material science, 2,4,6-Tris(4-ethynylphenyl)-1,3,5-triazine is utilized as a component in the synthesis of advanced materials with specific properties. Its ethynylphenyl groups and triazine ring can contribute to the creation of materials with tailored characteristics for various high-tech applications.

Upstream product

• 30363-03-2 2,4,6-tris(4-bromophenyl)-1,3,5-triazine 

Downstream Products

• 1418421-63-2 2,4,6-[4-(Cl(PEt₃)₂PtCC)C₆H₄]₃-1,3,5-C₃N₃ 
• 6091-44-7 piperidine hydrochloride 

Relevant articles and documents

Substituted 1,3,5-triazine hexacarboxylates as potential linkers for MOFs

Hexacarboxylates are promising linkers for MOFs such as NU-109 or NU-110, which possess large values for surfaces and pore volumina. Starting from 2,4,6-tris(bromoaryl)-1,3,5-triazines, palladium-catalyzed cross coupling reactions (Suzuki-Miyaura, Sonogas

Pillar[5]arene based conjugated macrocycle polymers with unique photocatalytic selectivity

The development of heterogeneous catalysts with substrate shape, size or electronic constitution selectivity is a huge challenge in photocatalysis. Reported herein is a host-guest interaction strategy to endow photocatalysts with special selectivity. By a

Fluorescent Sulphur- and Nitrogen-Containing Porous Polymers with Tuneable Donor–Acceptor Domains for Light-Driven Hydrogen Evolution

Light-driven water splitting is a potential source of abundant, clean energy, yet efficient charge-separation and size and position of the bandgap in heterogeneous photocatalysts are challenging to predict and design. Synthetic attempts to tune the bandgap of polymer photocatalysts classically rely on variations of the sizes of their π-conjugated domains. However, only donor–acceptor dyads hold the key to prevent undesired electron-hole recombination within the catalyst via efficient charge separation. Building on our previous success in incorporating electron-donating, sulphur-containing linkers and electron-withdrawing, triazine (C3N3) units into porous polymers, we report the synthesis of six visible-light-active, triazine-based polymers with a high heteroatom-content of S and N that photocatalytically generate H2 from water: up to 915 μmol h?1 g?1 with Pt co-catalyst, and—as one of the highest to-date reported values ?200 μmol h?1 g?1 without. The highly modular Sonogashira–Hagihara cross-coupling reaction we employ, enables a systematic study of mixed (S, N, C) and (N, C)-only polymer systems. Our results highlight that photocatalytic water-splitting does not only require an ideal optical bandgap of ≈2.2 eV, but that the choice of donor–acceptor motifs profoundly impacts charge-transfer and catalytic activity.

Tailored Band Gaps in Sulfur- and Nitrogen-Containing Porous Donor–Acceptor Polymers

Donor–acceptor dyads hold the key to tuning of electrochemical properties and enhanced mobility of charge carriers, yet their incorporation into a heterogeneous polymer network proves difficulty owing to the fundamentally different chemistry of the donor and acceptor subunits. A family of sulfur- and nitrogen-containing porous polymers (SNPs) are obtained via Sonogashira–Hagihara cross-coupling and combine electron-withdrawing triazine (C3N3) and electron-donating, sulfur-containing linkers. Choice of building blocks and synthetic conditions determines the optical band gap (from 1.67 to 2.58 eV) and nanoscale ordering of these microporous materials with BET surface areas of up to 545 m2 g?1 and CO2 capacities up to 1.56 mmol g?1. Our results highlight the advantages of the modular design of SNPs, and one of the highest photocatalytic hydrogen evolution rates for a cross-linked polymer without Pt co-catalyst is attained (194 μmol h?1 g?1).

Twinned Growth of Metal-Free, Triazine-Based Photocatalyst Films as Mixed-Dimensional (2D/3D) van der Waals Heterostructures

Design and synthesis of ordered, metal-free layered materials is intrinsically difficult due to the limitations of vapor deposition processes that are used in their making. Mixed-dimensional (2D/3D) metal-free van der Waals (vdW) heterostructures based on

A new class of star-shaped discotic liquid crystal containing a 2, 4, 6-triphenyl-1, 3, 5-triazine unit as a core

A new class of discotic liquid crystals based on 2, 4, 6-triphenyl-1, 3, 5-triazine as a core and [(4-alkoxyphenyl)ethynyl] benzene ester as rigid arms has been synthesized by a Pd(O)/Cu(I)-catalyzed carbon-carbon coupling reaction. The obtained compounds exhibited liquid-crystalline properties.