30363-03-2

Usage

Uses

2,?4,?6-?Tris-?(4-?bromophenyl)?[1,?3,?5]?triazine is a reagent used in the preparation of donor-acceptor dyads for enhancing the ability of charge carriers. Also a component in the discovery of dye-sensitized solar cells.

InChI:InChI=1/C21H12Br3N3/c22-16-7-1-13(2-8-16)19-25-20(14-3-9-17(23)10-4-14)27-21(26-19)15-5-11-18(24)12-6-15/h1-12H

Upstream product

• 623-00-7 4-bromobenzenecarbonitrile 
• 493-77-6 2,4,6-triphenyl-1,3,5-triazine 

Downstream Products

• 432551-44-5 2,4,6-tris[p-(2,2'-dipyridylamino)phenyl]-1,3,5-triazine 
• 31274-51-8 2,4,6-tris(1,1’-biphenyl-4-yl)-[1,3,5]triazine 
• 14544-47-9 4,4',4-(1,3,5‐triazine‐2,4,6‐triyl)trianiline 
• 23449-08-3 2-(4-bromobenzenyl)-4,6-diphenyl-1,3,5-triazine 
• 1253123-33-9 2,4,6-tri[p-(2-furyl)-phenyl]-1,3,5-triazine 
• 1253123-32-8 2,4,6-Tri[(5-thiophen-2-yl)-phenyl]-1,3,5-triazine 

Relevant academic research and scientific papers

Gas-Constructed Vesicles with Gas-Moldable Membrane Architectures

Integrating gas as a main building block into nanomaterial construction is a challenging mission that remains elusive. Herein, we report a gas-constructed vesicular system formed by CO2 gas and frustrated Lewis pairs (FLPs). Two molecular triad

High electron drift mobility in an amorphous film of 2,4,6,-tris[4-(1- naphthyl)phenyl]-1,3,5-triazine

2,4,6-Tris[4-(1-naphthyl)phenyl]-1,3,5-triazine exhibited a high electron drift mobility of 8.0 × 10-4 cm2 V-1 s-1.

A Hollow Microtubular Triazine- and Benzobisoxazole-Based Covalent Organic Framework Presenting Sponge-Like Shells That Functions as a High-Performance Supercapacitor

In this paper we report the construction of a hollow microtubular triazine- and benzobisoxazole-based covalent organic framework (COF) presenting a sponge-like shell through a template-free [3+2] condensation of the planar molecules 2,4,6-tris(4-formylphe

Structure and magnetic property of the organic triradical with triazine skeleton; 2,4,6-tris{p-(N-oxy-N-tert-butylamino)phenyl}triazine

1,3,5-tris{p-(N-oxy-N-tert-butylamino)phenyl}benzene (2) is known as a persistent triradical with a quartet ground state. A new triradical with a triazine skeleton was synthesized and characterized. The nitroxide triradical with triazine derivative 2,4,6-

Exploring the “Goldilocks Zone” of Semiconducting Polymer Photocatalysts by Donor–Acceptor Interactions

Water splitting using polymer photocatalysts is a key technology to a truly sustainable hydrogen-based energy economy. Synthetic chemists have intuitively tried to enhance photocatalytic activity by tuning the length of π-conjugated domains of their semic

Glass forming donor-substituted s-triazines: Photophysical and electrochemical properties

Triazine derived organic materials possessing various donor-chromophores at the periphery have been designed, synthesized and characterized. The synthesized compounds formed molecular glasses. Their glass transition temperatures ranged from 148 to 235 °C.

Twinned Growth of Metal-Free, Triazine-Based Photocatalyst Films as Mixed-Dimensional (2D/3D) van der Waals Heterostructures

Design and synthesis of ordered, metal-free layered materials is intrinsically difficult due to the limitations of vapor deposition processes that are used in their making. Mixed-dimensional (2D/3D) metal-free van der Waals (vdW) heterostructures based on

Functional Conjugated Polymers for CO2 Reduction Using Visible Light

The reduction of CO2 with visible light is a highly sustainable method for producing valuable chemicals. The function-led design of organic conjugated semiconductors with more chemical variety than that of inorganic semiconductors has emerged a

Tailored Band Gaps in Sulfur- and Nitrogen-Containing Porous Donor–Acceptor Polymers

Donor–acceptor dyads hold the key to tuning of electrochemical properties and enhanced mobility of charge carriers, yet their incorporation into a heterogeneous polymer network proves difficulty owing to the fundamentally different chemistry of the donor and acceptor subunits. A family of sulfur- and nitrogen-containing porous polymers (SNPs) are obtained via Sonogashira–Hagihara cross-coupling and combine electron-withdrawing triazine (C3N3) and electron-donating, sulfur-containing linkers. Choice of building blocks and synthetic conditions determines the optical band gap (from 1.67 to 2.58 eV) and nanoscale ordering of these microporous materials with BET surface areas of up to 545 m2 g?1 and CO2 capacities up to 1.56 mmol g?1. Our results highlight the advantages of the modular design of SNPs, and one of the highest photocatalytic hydrogen evolution rates for a cross-linked polymer without Pt co-catalyst is attained (194 μmol h?1 g?1).

Fluorescent Sulphur- and Nitrogen-Containing Porous Polymers with Tuneable Donor–Acceptor Domains for Light-Driven Hydrogen Evolution

Light-driven water splitting is a potential source of abundant, clean energy, yet efficient charge-separation and size and position of the bandgap in heterogeneous photocatalysts are challenging to predict and design. Synthetic attempts to tune the bandgap of polymer photocatalysts classically rely on variations of the sizes of their π-conjugated domains. However, only donor–acceptor dyads hold the key to prevent undesired electron-hole recombination within the catalyst via efficient charge separation. Building on our previous success in incorporating electron-donating, sulphur-containing linkers and electron-withdrawing, triazine (C3N3) units into porous polymers, we report the synthesis of six visible-light-active, triazine-based polymers with a high heteroatom-content of S and N that photocatalytically generate H2 from water: up to 915 μmol h?1 g?1 with Pt co-catalyst, and—as one of the highest to-date reported values ?200 μmol h?1 g?1 without. The highly modular Sonogashira–Hagihara cross-coupling reaction we employ, enables a systematic study of mixed (S, N, C) and (N, C)-only polymer systems. Our results highlight that photocatalytic water-splitting does not only require an ideal optical bandgap of ≈2.2 eV, but that the choice of donor–acceptor motifs profoundly impacts charge-transfer and catalytic activity.