460745-20-4Relevant articles and documents
Efficient synthesis of building blocks for branched rhamnogalacturonan i fragments
Pogosyan, Amayak,Gottwald, Andreas,Michalik, Dirk,Endress, Hans-Ulrich,Vogel, Christian
, p. 9 - 15 (2013/10/01)
Starting from allyl 2-O-acetyl-3-O-benzyl-α-l-rhamnopyranoside (3), allyl (2,3,4,6-tetra-O-benzoyl-β-d-galactopyranosyl)-(1→4)-2-O-acetyl- 3-O-benzyl-α-l-rhamnopyranoside (5) was synthesized under Helferich conditions. Module 5 was converted to 2,3,4,6-te
Total synthesis of woodrosin I - Part 1: Preparation of the building blocks and evaluation of the glycosylation strategy
Fuerstner, Alois,Jeanjean, Fabien,Razon, Patrick,Wirtz, Conny,Mynott, Richard
, p. 307 - 319 (2007/10/03)
The preparation of three building blocks required for the total synthesis of woodrosin I (1) is outlined, a complex resin glycoside bearing a macrolide ring which spans four of the five sugars of its oligosaccharide backbone. Key steps involve the enantio
Total synthesis of woodrosin I
Fuerstner, Alois,Jeanjean, Fabien,Razon, Patrick
, p. 2097 - 2101 (2007/10/03)
The reliability of ring-closing metathesis, even in complex cases, is highlighted in the first total synthesis of the structurally intriguing resin glycoside woodrosin I (1). The synthesis also shows the maturity of the trichloroacetimidate method for gly