485810-84-2

Basic information

• Product Name: Benzoic acid, 5-methoxy-2-(methylamino)-, ethyl ester (9CI)
• Synonyms: Benzoic acid, 5-methoxy-2-(methylamino)-, ethyl ester (9CI)
• CAS NO: 485810-84-2
• Molecular Formula: C11H15NO3
• Molecular Weight: 209.2417
• Product Categories: AMINOACID
• Mol File: 485810-84-2.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzoic acid, 5-methoxy-2-(methylamino)-, ethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 5-methoxy-2-(methylamino)-, ethyl ester (9CI)(485810-84-2)
• EPA Substance Registry System: Benzoic acid, 5-methoxy-2-(methylamino)-, ethyl ester (9CI)(485810-84-2)

Safety Data

• Hazardous Substances Data: 485810-84-2(Hazardous Substances Data)

Upstream product

• 18437-68-8 tert-butyl N-(4-methoxyphenyl)carbamate 
• 104-94-9 4-methoxy-aniline 
• 64-17-5 ethanol 
• 201230-82-2 carbon monoxide 
• 5961-59-1 N-methyl-N-(4-methoxyphenyl)amine 

Relevant articles and documents

Palladium-catalyzed oxidative carbonylation of aromatic C-H bonds of N -alkylanilines with CO and alcohols for the synthesis of o -aminobenzoates

A Pd(II)-catalyzed C-H monocarbonylation of N-alkylanilines for the synthesis of o-aminobenzoates has been developed. Various aliphatic alcohols and phenol were tolerated in the reaction to afford the corresponding o-aminobenzoates in good yields under mild balloon pressure of CO.

Palladium/copper-catalyzed aerobic oxidative C-H carbonylation for the synthesis of o-aminobenzoates

The palladium/copper-catalyzed aerobic oxidative C-H carbonylation for the synthesis of o-aminobenzoates is described. Molecular oxygen is used as the terminal oxidant. This methodology proceeds with a wide range of N-substituted anilines and alcohols and gives straightforward access to valuable o-aminobenzoates.