Diastereoselective synthesis of diketopiperazine bis-α,β- epoxides
Functionalized diketopiperazines (dioxopiperazines) are an important class of molecules in medicinal chemistry and material science. Herein we report a diastereoselective synthesis of diketopiperazine bis-α,β-epoxides via the oxidation of exocyclic olefin
Ando, Shin,Grote, Amy L.,Koide, Kazunori
supporting information; experimental part
p. 1155 - 1158
(2011/04/24)
Synthesis of dehydroamino acids and didehydrodioxopiperazines and their conversion into α-mercapto-α-amino acid derivatives
A synthesis of α,β-dehydroamino acid derivatives 12 is described, which is of possible general applicability and might be useful for the preparation of peptides which have such a moiety in their sequence.I addition, several didehydrodioxopiperazines (13-1
Herscheid, Jacobus D. M.,Scholten, Henk P. H.,Tijhuis, Marian W.,Ottenheim, Harry C. J.
p. 73 - 78
(2007/10/02)
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