51177-68-5

Basic information

• Product Name: Pt(1,5-cyclooctadiene)(Ph)(I)
• Synonyms: Pt(1,5-cyclooctadiene)(Ph)(I)
• CAS NO: 51177-68-5
• Molecular Weight: 507.273
• Mol File: 51177-68-5.mol

Chemical Properties

• CAS DataBase Reference: Pt(1,5-cyclooctadiene)(Ph)(I)(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(1,5-cyclooctadiene)(Ph)(I)(51177-68-5)
• EPA Substance Registry System: Pt(1,5-cyclooctadiene)(Ph)(I)(51177-68-5)

Safety Data

• Hazardous Substances Data: 51177-68-5(Hazardous Substances Data)

Upstream product

• 12266-72-7 1,5-cyclooctadienediiodoplatinum(II) 
• 960-16-7 tributylphenylstannane 
• 12080-32-9 dichloro( 1,5-cyclooctadiene)platinum(ll) 

Downstream Products

• 478294-13-2 Pt(C₈H₁₂)(CH₂COCH₃)2 
• 478294-12-1 Pt(CH₂COMe)(Ph)(cod) 
• 899826-05-2 [Pt(Ph)(bpy)(cod)](PF₆) 
• 478294-15-4 [Pt(COD)(phenyl)(acetone-d6)][BF₄] 
• 899439-57-7 PtI(COPh)(cod) 

Relevant articles and documents

Synthesis of platinum-iodo-alkyl/aryl complexes in ligand-exchange reactions: Determination of the structure of Pt{(S,S)-bdpp}(X)I complexes (X = Me, I) by X-ray crystallography

Pt{(S,S)-bdpp}(R)I (bdpp = 2,4-bis(diphenylphosphino)pentane; R = Me, Ph, Bz, 2-Tioph) complexes were formed in alkyl/aryl ligand - iodide ligand-exchange reactions by reacting the corresponding Pt{(S,S)-bdpp}R2 complexes with methyl iodide. Th

Intermolecular Phenyl Ligand Transfer of Pt(II) and Pd(II) Complexes with Bidentate Ligand

[PtPh2(dppe)] (dppe = 1,2-bis(diphenylphosphino)ethane) reacts with equimolar [PtCl2(cod)] (cod = 1,5-cyclooctadiene) to give a mixture of [PtPh2(cod)] (38%), [PtCl(Ph)(cod)] (53%) and [PtCl 2(dppe)] (72%) via exchange of the phenyl and chloro ligands among the Pt complexes. The reaction is strongly inhibited by addition of Cl -. The intermolecular phenyl ligand transfer from Pd to Pt is observed in the reaction of [PdCl(Ph)(bpy)] (bpy = 2,2′-bipyridine) with [PtX2(cod)] (X = Cl, I), which produces [PtX(Ph)(cod)]. The reaction of [PdCl(Ph)(bpy)] with [PdCl2(cod)], giving [Pd2(μ -Cl)2 {(4,5-η-κC1)-(C8H 12Ph)}2], occurs much faster than a similar reaction of [PdCl(Ph)(bpy)] with [PtCl2(cod)]. [PtPh2(L2)] (L2 = cod, dppe) reacts with [PdCl2(cod)] in CH 2Cl2 at room temperature to afford [Pd2(μ -Cl)2{(4,5-η-κC1)-(C8H 12Ph)}2] via intermolecular phenyl ligand transfer from Pt to Pd and subsequent insertion of a C=C bond of cod into the Pd-Ph bond. Cationic Pd complexes [Pd(acetone)2(cod)]2+(BF 4-)2 and [Pd(η3-C 3H5)(acetone)2]+(BF4-) react with [PtPh2(cod)] to form biphenyl. All these results indicate that chloro complexes of Pd and Pt with cod ligand undergo the ligand exchange with the phenyl complexes of these metals.