cas 516-88-1, (22E)-5α-Ergosta-8,14,22-trien-3β-ol | Articles data ｜lookchem

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516-88-1

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REGIOCONTROLLED SYNTHESIS OF THE ERGOSTEROL B-ISOMERS
A novel, regiocontrolled synthesis of the ergosterol B-isomers, (1), (2) and (3) is described, the success of which was realized via the highly regioselective formation of intermediate trienoltriflates, (7), (8) and (9).
Dolle, Roland E.,Schmidt, Stanley J.,Kruse, Lawrence I.
p. 1581 - 1582
(2007/10/02)

Studies on the Acid-Catalyzed Homonuclear Steroidal Diene Isomerization.
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Dolle, Roland E.,Schmidt, Stanley J.,Eggleston, Drake,Kruse, Lawrence I.
p. 1563 - 1566
(2007/10/02)

Structure and Chemistry of ?-Allyl Palladium Complexes from Steroids
The synthesis and structures of ?-allyl palladium complexes prepared from vitamins D2 and D3 and from ergosterol, 7,8-didehydrocholesterol, and 3-epi-cholesterol are described.The mechanism of palladisation is descussed as well as the transformation of the complexes into conjugated trienes or allylic alcohols.
Mahe, Christian,Patin, Henri,Hulle, Marie-Therese Van,Barton, Derek H.R.
p. 2504 - 2508
(2007/10/02)

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PSA: 20.23000
LogP: 7.47490

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