5573-62-6

Basic information

• Product Name: (ETHYLTHIO)TRIMETHYLSILANE
• Synonyms: 2-(ETHYLTHIO)TRIMETHYLSILANE;(ETHYLTHIO)TRIMETHYLSILANE;(ETHYLTHIO)TRIMETHYLSILANE, TECH., 90%;(ETHYLTHIO)TRIMETHYLSILANE TECH 90%;(Ethylthio)trimethylsilanetech90%;ethyl trimethylsilyl sulfide;Ethyl trimethylsilyl sulfide, Trimethylsilyl ethyl sulfide;(Ethylthio)trimethylsilane,96%
• CAS NO: 5573-62-6
• Molecular Formula: C₅H₁₄SSi
• Molecular Weight: 134.32
• Product Categories: Aliphatics;Sulfur & Selenium Compounds
• Mol File: 5573-62-6.mol

Chemical Properties

• Melting Point: 128 °C
• Boiling Point: 69-70 °C100 mm Hg(lit.)
• Flash Point: 62 °F
• Appearance: /
• Density: 0.83 g/mL at 25 °C(lit.)
• Vapor Pressure: 12mmHg at 25°C
• Refractive Index: n20/D 1.45(lit.)
• Storage Temp.: Flammables area
• Solubility: Chloroform, Hexanes
• CAS DataBase Reference: (ETHYLTHIO)TRIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: (ETHYLTHIO)TRIMETHYLSILANE(5573-62-6)
• EPA Substance Registry System: (ETHYLTHIO)TRIMETHYLSILANE(5573-62-6)

Safety Data

• Hazard Codes: F
• Statements: 11
• Safety Statements: 16-29-33
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 3
• F: 10-13-21
• HazardClass: 3.1
• PackingGroup: II
• Hazardous Substances Data: 5573-62-6(Hazardous Substances Data)

Usage

Chemical Properties

(ETHYLTHIO)TRIMETHYLSILANE is clear colorless liquid

Uses

(ETHYLTHIO)TRIMETHYLSILANE is used in the syntesis of azasilasulfonium salts.

General Description

(Ethylthio)trimethylsilane is reported to participate in the synthesis of adenophostin A and analog. It reacts with primary and secondary amines to yield aminosilane and ethanethiol.

InChI:InChI=1/C5H14SSi/c1-5-6-7(2,3)4/h5H2,1-4H3

Upstream product

• 18156-74-6 1-(Trimethylsilyl)imidazole 
• 75-08-1 ethanethiol 
• 43112-38-5 3-(trimethylsilyl)-2-oxazolidinone 
• 516511-16-3 bis(ethylthio)diphenylgermane 
• 2857-97-8 trimethylsilyl bromide 
• 994-45-6 triethyl(ethylthio)stannane 

Downstream Products

• 51736-81-3 (Ethylsulfanyl-phenyl-methyl)-trimethyl-silane 
• 42893-53-8 S-ethyl thiocinnamate 
• 1484-17-9 S-ethyl thiobenzoate 
• 20033-61-8 Diethyldithioimidocarbonat 
• 30543-40-9 Ethylthiochlorformimidat 
• 21114-90-9 2-Ethyl-1,1-dimethyl-3-phenyl-isothiourea 
• 51892-23-0 S-ethyl 2-methoxybenzothioate 
• 1870-68-4 bis-ethylsulfanyl-phenyl-borane 
• 27486-24-4 (ethylthio)trifluorophenyl-phosphorane 
• 27486-21-1 Ethylthio(difluor)diphenylphosphoran 
• 53963-34-1 (E)-3-phenyl-1-[bis(ethylthio)]prop-2-ene 
• 1486-39-1 S,S,S-triethyl phosphorotrithioate 
• 27482-20-8 cyclohexanone-diethyldithioacetal 
• 59340-48-6 <α-(ethylthio)benzyloxy>trimethylsilane 

Relevant articles and documents

Plasmochemical synthesis of thin layers of the sulfur doped silicon dioxide

Plasmochemical synthesis of thin layers of the sulfur atoms doped SiO 2 on the basis of volatile Siorganoelement compounds containing the Si-S fragments was studied. Highly pure trimethyl-ethylthiosilane Me 3SiSEt was used as a precu

Improved Direct Preparation of O-Trimethylsilyl Monothioacetals from Thiols and Carbonyl Compounds

Preparation of 1-alkylthio- or 1-phenylthio-1-trimethylsiloxyalkanes and -cycloalkanes directly from carbonyl compounds and thiols, is achieved using 1-trimethylsilylimidazole and trimethylsilyl triflate as a catalyst.

Reagents and synthetic methods. 31. Silylations with N-trimethylsilyl-2-oxazolidinone (TMSO)

Silylation of ketones, alcohols, mercaptans, and carboxylic acids with N-trimethylsilyl-2-oxazolidinone (TMSO) and triflic acid as catalyst has been described from synthetic and mechanistic points of view.