27482-20-8

Basic information

• Product Name: Cyclohexane, 1,1-bis(ethylthio)-
• CAS NO: 27482-20-8
• Molecular Formula: C10H20S2
• Molecular Weight: 204.401
• Mol File: 27482-20-8.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 1,1-bis(ethylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 1,1-bis(ethylthio)-(27482-20-8)
• EPA Substance Registry System: Cyclohexane, 1,1-bis(ethylthio)-(27482-20-8)

Safety Data

• Hazardous Substances Data: 27482-20-8(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 75-08-1 ethanethiol 
• 119968-51-3 O-trimethylsilylcyclohexanone hemiethylthioketal 
• 1056477-06-5 2-bromocyclohexanone 
• 6802-76-2 ethyl 2-cyano-2-cyclohexylideneacetate 
• 822-87-7 2-Chlorocyclohexanone 
• 177-10-6 1,3-dioxolane-2-spirocyclohexane 
• 81375-98-6 4,4-bis(ethylsulfanyl)but-3-en-2-one 
• 5573-62-6 (ethylthio)trimethylsilane 

Downstream Products

• 60340-38-7 1-Ethylsulfanyl-cyclohexanecarbonitrile 
• 1084851-96-6 ethyl N-2,6-dichlorophenyl-1-(ethylthio)cyclohexanecarbimidothioate 
• 1084852-14-1 C₂₄H₂₆Cl₄N₂S₂ 
• 766-05-2 cyclohexane carbonitrile 
• 108-94-1 cyclohexanone 
• 682-91-7 ethyl ethanethiosulfonate 
• 36056-40-3 Cyclohexyliden-thioessigsaeure-aethylester 
• 500356-77-4 1,1-bis-ethanesulfonyl-cyclohexane 
• 7133-25-7 cyclohexyl ethyl sulfide 
• 15786-70-6 cyclohexenyl ethyl sulfide 

Relevant articles and documents

Chemoselective and odorless transthioacetalization of acetals using α-oxo-ketene dithioacetals as thiol equivalents

Using α-oxo-ketene dithioacetals 1a as odorless thiol equivlents, an efficient and odorless transthioacetalization of acetals 2 has been developed. In the presence of MeCOCl in MeOH, the cleavage of 1a commences to generate thiols at both room and reflux temperatures, and the generated thiols then react with acetals 2 to give correspecting thioacetals 3 in good yield. This transthioacetalization is characterized by mild reaction conditions, simple procedure, good yields, and perfect chemoselectivity. It is noteworthy that only a very faint odor of thiols can be perceived during both the reaction and workup.

Silica-PCl5: A novel heterogenous catalyst for simple and efficient chemoselective protection of carbonyl compounds

A simple, efficient and environmentally benign procedure has been developed for chemoselective protection of carbonyl compounds using the newly developed heterogeneous catalyst: Silica-PCl5. A variety of aldehydes and ketones were efficiently c

Simple, mild and efficient thioacetalization and transthioacetalization of carbonyl compounds and deprotection of thioacetals: Unique role of thiols in the selectivity of thioacetalization

Silica supported sodium hydrogen sulfate (NaHSO4·SiO 2) has been employed for efficient thioacetalization and transthioacetalization of carbonyl compounds in CH2Cl2 at room temperature. Selectivity of thioacetalization was dependent on the thiols used for the conversion. The same catalyst was also found to be effective for deprotection of thioacetals in CH2Cl2-H2O at room temperature.