5915-41-3

Basic information

• Product Name: Terbutylazine
• Synonyms: 2-tert.butylamino-4-aethylamino-6-chlor-1,3,5-triazin;3,5-Triazine-2,4-diamine,6-chloro-n-(1,1-dimethylethyl)-n’-ethyl-1;5-triazine-2,4-diamine,6-chloro-n-(1,1-dimethylethyl)-n’-ethyl-3;caswellnumber125b;chlorcaragard;epapesticidecode080814;G 13529;g13529
• CAS NO: 5915-41-3
• Molecular Formula: C₉H₁₆ClN₅
• Molecular Weight: 229.71
• EINECS: 227-637-9
• Product Categories: Standards for SupelMIPTM SPEAlphabetic;Alpha sort;Chromatography;Herbicides;Pesticides&Metabolites;Q-ZAnalytical Standards;TA - TEPesticides&Metabolites;Triazines;Alphabetic;Agro-Products;Amines;Bases & Related Reagents;Heterocycles;Nucleotides
• Mol File: 5915-41-3.mol

Chemical Properties

• Melting Point: 178°C
• Boiling Point: 368.7°C (rough estimate)
• Flash Point: 11 °C
• Appearance: /
• Density: 1.1880
• Vapor Pressure: 9.19E-06mmHg at 25°C
• Refractive Index: 1.6110 (estimate)
• Storage Temp.: APPROX 4°C
• PKA: 2.69±0.10(Predicted)
• Water Solubility: 5mg/L(20 oC)
• BRN: 3951137
• CAS DataBase Reference: Terbutylazine(CAS DataBase Reference)
• NIST Chemistry Reference: Terbutylazine(5915-41-3)
• EPA Substance Registry System: Terbutylazine(5915-41-3)

Safety Data

• Hazard Codes: F,T,Xn
• Statements: 11-23/24/25-39/23/24/25-22
• Safety Statements: 7-16-24-45-36-36/37
• RIDADR: UN1230 3/PG 2
• WGK Germany: 2
• RTECS: XY4550000
• Hazardous Substances Data: 5915-41-3(Hazardous Substances Data)

Usage

Uses

A triazine herbicide.

Definition

ChEBI: A diamino-1,3,5-triazine that is N-tert-butyl-N'-methyl-1,3,5-triazine-2,4-diamine substituted by a chloro group at position 6.

InChI:InChI=1/C9H16ClN5/c1-5-11-7-12-6(10)13-8(14-7)15-9(2,3)4/h5H2,1-4H3,(H2,11,12,13,14,15)

Upstream product

• 27282-85-5 2,4-dichloro-6-t-butylamino-1,3,5-triazine 
• 75-04-7 ethylamine 

Downstream Products

• 886-50-0 terbutryn 
• 645-92-1 ammeline 
• 645-93-2 ammelide 
• 108-80-5 isocyanuric acid 
• 3397-62-4 2-Chloro-4,6-diamino-1,3,5-triazine 
• 30125-63-4 deethylterbuthylazine 
• 1007-28-9 Deisopropylatrazine 

Relevant articles and documents

Continuous production method of multi-kettle serial triazine herbicide

The invention relates to a continuous production method of a multi-kettle serial triazine herbicide. A metered cyanuric chloride solution is pre-cooled and mixed with alkylamine R1 in a mixer to entera first-stage reaction kettle, continuous discharging is conducted, after a heat exchanger is passed, the cyanuric chloride solution is neutralized with alkali in the mixer and enters a first-stage neutralization kettle, after a reaction is completed, the cyanuric chloride solution passes through a continuous water separator and the heat exchanger and is mixed with alkylamine R2 in the mixer to enter a second-stage reaction kettle, the continuous discharging is conducted, after the cyanuric chloride solution passes through the heat exchanger, the cyanuric chloride solution is mixed with the alkali in the mixer to enter a second-stage neutralization kettle, after the neutralization, a aqueous phase is separated by a continuous layerer, a solvent is removed, and drying is conducted to obtain a triazine product. The production method has the advantages of high productivity, good production stability, high efficiency, high product quality and the like, is particularly suitable for technical transformation of existing production enterprises, has a low transformation cost, basically does not add novel reaction equipment, and is easily mastered by existing enterprises.

Herbicidal mixtures having a synergistic effect

PCT No. PCT/EP96/03996 Sec. 371 Date Feb. 17, 1998 Sec. 102(e) Date Feb. 17, 1998 PCT Filed Sep. 12, 1996 PCT Pub. No. WO97/10714 PCT Pub. Date Mar. 27, 1997A composition comprising at least one sulfonylurea of the formula I wherein R1 is substituted alkyl; halogen; a group ER6 (E=O, S or NR7); COOR8; NO2; S(O)oR9; SO2NR10R11; or CONR10R11; R2 is hydrogen, alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkoxy, haloalkyl, alkylsulfonyl, nitro, cyano or alkylthio; R3 is F, CF3, CF2Cl, CF2H, OCF3, OCF2Cl, or, if R1 is CO2CH3 and R2 is simultaneously fluorine, R3 is Cl, or, if R1 is CH2CF3 or CF2CF3, R3 is methyl, or, if R4 is OCF3 or OCF2Cl, R3 is OCF2H or OCF2Br; R4 is alkoxy, alkyl, alkylthio, alkylamino, dialkylamino, halogen, haloalkyl or haloalkoxy; and R5 is hydrogen, alkoxy or alkyl; or an enviromentally compatible salt of I, and an aryloxyalkanoic acid selected from the group consisting of 2,4-D, 2,4-DB, clomeprop, dichlorprop, dichlorprop-P, dichlorprop-P (2,4-DP-P), fenoprop (2,4,5-TP), fluoroxypyr, MCPA, MCPB, mecoprop, mecoprop-P, napropamide, napropanilide, triclopyr, and an enviromentally compatible salt thereof exhibits a synergistic herbicidal effect.

Herbicidal compositions comprising diamino-1,3,5-triazine and chloroacetanilide herbicides and a surfactant system

Flowable herbicidal compositions which contain an active component combination of at least one triazine and at least one chloroacetanilide with a surfactant component. This surfactant component, which consists of an anionic compound based on a monosulfuric acid ester of alkyl or alkyphenol polyglycol ethers as well as at least one nonionic alkyl or alkylphenol polyglycol ether, gives stable dispersions of the concentrated composition and forms stable dispersions of dilutions of the compositions suitable for direct use.

Pesticide-polymer systems prepared from vinyl monomers

Controlled release pesticide-polymer systems are prepared by the polymerization of vinyl monomers containing pendant pesticides. The vinyl monomers are prepared by reacting an acrylic acid derivative with a pesticide or a pesticide derivative having an active hydrogen. The pesticide-polymer systems prepared from the pesticide vinyl monomers release the active pesticide material by hydrolysis or chemical depolymerization under conditions of use.

Process for the production of chloro-amino-s-triazines

2-CHLORO-S-TRIAZINE SUBSTITUTED IN AT LEAST ONE OF THE POSITIONS 4,6 OF THE TRIAZINE RING WITH AN AMINO GROUP IS OBTAINED BY FEEDING SEPARATELY AN AQUEOUS AMINE SOLUTION AND AN AQUEOUS NaOH solution into a water-organic liquid reaction medium containing cyanuric chloride, delivering to said medium per unit of time from 1.05 to 1.30 moles of amine for each mole of sodium hydroxide, feeding the amine solution until an amount of from 1 to 2 moles of amine per mole of cyanuric chloride is reached in the medium and the NaOH solution until an amount in moles equal to or slightly higher than the amount of amine moles fed in is reached in the medium. The temperature of the reaction medium is maintained at a value of from 5°-15° C to 60°-70° C during the feeding period.