74228-24-3Relevant articles and documents
Method for preparing N,N-Dimethylaniline compound through alkylation of alkyl tosylate
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Paragraph 0073; 0075, (2019/07/11)
The invention provides a method for preparing a N,N-Dimethylaniline compound through alkylation of alkyl tosylate, and belongs to the technical field of organic synthesis. According to the method, paratoluensulfonyl chloride and fatty alcohol serve as raw materials, pyridine serves as an acid-binding agent, and the alkyl tosylate is generated; the alkyl tosylate as an alkylation reagent and an aniline compound are alkylated under the alkaline condition to obtain the N,N-Dimethylaniline compound. The method is implemented at normal pressure, the operation is simple, no waste acid is generated,the yield and the purity are high, and the method is suitable for industrial and scaled production.
Preparation method of disperse blue 354
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Paragraph 0035; 0058-0059, (2019/02/06)
The invention relates to a preparation method of disperse blue 354. The preparation method is characterized by comprising the following steps: preparing a compound Ib, wherein methanol is used as a solvent, with the existence of pyridine, a compound Ia reacts with malononitrile in a mass ratio of 1: (0.4 to 0.5), and the reaction temperature is 45 DEG C to a reflux temperature of the methanol. Byadopting the preparation method, the consumption of malononitrile can be reduced, the reaction condition is mild, harmful substances can be reduced, and a product is good in purity and high in yield.The preparation method is low in initial raw material cost, and high in total yield.