3839-35-8

Basic information

• Product Name: P-TOLUENESULFONIC ACID N-HEXYL ESTER
• Synonyms: HEXYL P-TOLUENESULFONATE;P-TOLUENESULFONIC ACID N-HEXYL ESTER;P-TOLUENESULFONIC ACID HEXYL ESTER;Toluenesulfonicacidhexylester;4-Methylbenzenesulfonic acid hexyl ester;Hexyl p-Toluenesulfonate;Hexyl 4-methylbenzenesulfonate
• CAS NO: 3839-35-8
• Molecular Formula: C₁₃H₂₀O₃S
• Molecular Weight: 256.36
• Mol File: 3839-35-8.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 197 °C / 2mmHg
• Flash Point: 174.1°C
• Appearance: /
• Density: 1,09 g/cm3
• Refractive Index: 1.4980 to 1.5010
• CAS DataBase Reference: P-TOLUENESULFONIC ACID N-HEXYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: P-TOLUENESULFONIC ACID N-HEXYL ESTER(3839-35-8)
• EPA Substance Registry System: P-TOLUENESULFONIC ACID N-HEXYL ESTER(3839-35-8)

Safety Data

• Hazardous Substances Data: 3839-35-8(Hazardous Substances Data)

Usage

Uses

Hexyl p-Toluenesulfonate is a reactant in the synthesis of 7-bromo-5-(2''-chlorophenyl)-3-hydroxy-1-methyl-1,2-dihydro-3H-1,4-benzodiazepin-2-one 1 and 7-bromo-5-(2''-chloro)phenyl-1-hexyl-1,2,4,5-tetrahydro-3H-1,4-benzodiazepin-2,3-dione. Also, it is used to synthesize carbazates.

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 111-27-3 hexan-1-ol 
• 6095-42-7 tri-n-hexyl phosphite 
• 104-15-4 toluene-4-sulfonic acid 
• 94957-45-6 n-butylethynyl tosylate 
• 27126-76-7 [hydroxy(tosyloxy)iodo]benzene 
• 94957-42-3 n-hexynyl(phenyl)iodonium tosylate 
• 75351-33-6 (6-hydroxyhexyl)tosylate 
• 1680206-12-5 Grushin’s reagent 
• 6926-45-0 1-azidohexane 
• 111-25-1 1-bromo-hexane 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 7182-86-7 tetrabutylammonium p-toluenesulfonate 
• 638-45-9 1-Iodohexane 

Downstream Products

• 35216-11-6 7-tetradecyne 
• 59693-91-3 n-Hexyl-p-chlorphenylsulfid 
• 5342-83-6 hexyl(4-methylphenyl)sulfane 
• 885620-30-4 hexyl 3-hydroxy-4-nitrobenzoate 
• 885620-29-1 hexyl 4-hydroxy-3-nitrobenzoate 
• 7461-26-9 hexyl N-phenyl-carbamate 
• 137615-41-9 (+)-4-benzyloxy-1-(1-hexyloxy-2,2,2-trifluoroethyl)benzene 
• 172154-63-1 2-(3,5-di-tert-butyl-4-hydroxyphenyl)-6-n-hexyloxypurine 
• 119838-77-6 (+)-benzyl 4-(1hexyloxyethyl)benzoate 
• 1327337-34-7 1-(benzyloxy)-4-(2-hexyloxyethyl)benzene 
• 1381777-43-0 7-bromo-5-(2-chlorophenyl)-1-hexyl-1,2,4,5-tetrahydro-3H-1,4-benzodiazepine-2,3-dione 
• 38409-62-0 methyl 3-hexylbenzoate 
• 28593-15-9 1-fluoro-3-hexylbenzene 
• 90525-97-6 4-hexyl-N,N-dimethylbenzamide 

Relevant articles and documents

Synthesis of polyfluorinated ethers

Procedures for preparing polyfluorinated ethers H(CF2CF 2)nCH2OR by alkylation of the corresponding telomeric alcohols H(CF2CF2)nCH2OH (n = 1-3) with alkyl halides and alkyl tosylates were examined.

Combinatorial discovery of thermoresponsive cycloammonium ionic liquids

This work demonstrated, for the first time, the combinatorial discovery and rational identification of small-molecule cycloammonium-based thermoresponsive ionic liquids that exhibit LCST phase transition and carry attractiveTcvalues in water.

Ionic liquid brush as an efficient and reusable heterogeneous catalytic assembly for the tosylation of phenols and alcohols in neat water

A very efficient and reusable heterogeneous ionic liquid brush assembly was developed. The catalyst exhibits high catalytic activity for the tosylation of phenols and alcohols in neat water. Moreover, the catalyst shows outstanding stability and reusability, and it can be simply and effectively recovered and reused five times without noticeable loss of catalytic activity.