832079-33-1

Basic information

• Product Name: 1,2-BIS(TRIMETHOXYSILYL)DECANE
• Synonyms: 1,2-BIS(TRIMETHOXYSILYL)DECANE;Trimethoxy(1-Trimethoxysilyldecan-2-yl)silane
• CAS NO: 832079-33-1
• Molecular Formula: C16H38O6Si2
• Molecular Weight: 382.64
• Mol File: 832079-33-1.mol

Chemical Properties

• Boiling Point: 130-132°C 0,4mm
• Flash Point: 140.9°C
• Appearance: /
• Density: 0,984 g/cm3
• Vapor Pressure: 0.000138mmHg at 25°C
• Refractive Index: 1.4303
• CAS DataBase Reference: 1,2-BIS(TRIMETHOXYSILYL)DECANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-BIS(TRIMETHOXYSILYL)DECANE(832079-33-1)
• EPA Substance Registry System: 1,2-BIS(TRIMETHOXYSILYL)DECANE(832079-33-1)

Safety Data

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39
• TSCA: No
• Hazardous Substances Data: 832079-33-1(Hazardous Substances Data)

Usage

Uses

Used in Chemical Manufacturing Industry:
1,2-BIS(TRIMETHOXYSILYL)DECANE is used as a silane coupling agent for improving the adhesion and bonding strength between organic and inorganic materials. This application is crucial in the production of silicone rubber, adhesives, and sealants, ensuring the durability and performance of these products.
Used in Corrosion Protection:
1,2-BIS(TRIMETHOXYSILYL)DECANE is studied for its potential as a corrosion protection agent. Its ability to bond with both organic and inorganic materials can provide a protective layer against corrosive elements, extending the lifespan of materials and structures.
Used in Surface Modification:
As a surface modifier, 1,2-BIS(TRIMETHOXYSILYL)DECANE can alter the properties of materials, such as wettability, adhesion, and biocompatibility. This application is beneficial in various industries, including electronics, textiles, and biomedical engineering, where surface properties play a critical role in product performance.
Used in Nanocomposites Industry:
1,2-BIS(TRIMETHOXYSILYL)DECANE is also considered as a modifier for nanocomposites. Its incorporation can enhance the mechanical, thermal, and electrical properties of nanocomposite materials, making them suitable for high-performance applications in aerospace, automotive, and construction industries.
Safety Precautions:
Due to its flammable and irritant properties, 1,2-BIS(TRIMETHOXYSILYL)DECANE should be handled with care. Proper safety measures, such as using personal protective equipment and following safety guidelines, should be taken to minimize risks during its use and handling.

InChI:InChI=1/C16H38O6Si2/c1-8-9-10-11-12-13-14-16(24(20-5,21-6)22-7)15-23(17-2,18-3)19-4/h16H,8-15H2,1-7H3

Upstream product

• 1445-45-0 Trimethyl orthoacetate 
• 620987-03-3 1,2-bis(trichlorosilyl)decane 
• 149-73-5 trimethyl orthoformate 
• 872-05-9 1-Decene 
• 67-56-1 methanol 
• 832079-34-2 1-trichlorosilyl-2-dichlorosilyldecane 

Relevant articles and documents

Enhanced hydrolytic stability of siliceous surfaces modified with pendant dipodal silanes

Dipodal silanes possess two silicon atoms that can covalently bond to a surface. They offer a distinct advantage over conventional silanes commonly used for surface modification in terms of maintaining the integrity of surface coatings, adhesive primers, and composites in aqueous environments. New nonfunctional and functional dipodal silanes with structures containing pendant rather than bridged organofunctionality are introduced. The stability of surfaces in aqueous environments prepared from dipodal silanes with hydrophobic alkyl functionality is compared to the stability of similar surfaces prepared from the conventional silanes. In strongly acidic and brine environments, surfaces modified with dipodal silanes demonstrate markedly improved resistance to hydrolysis compared to surfaces prepared from conventional silanes. Pendant dipodal silanes exhibit greater stability than bridged dipodal silanes. The apparent equilibrium constant for the formation of silanol species by the hydrolysis of a disiloxane bond was determined as Kc=[SiOH]2/[Si-O-Si][H2O]= 6±1×10-5 and is helpful in understanding the enhanced hydrolytic stability of surfaces modified with dipodal silanes. Two feet are better than one! Nonfunctional and functional dipodal silanes with structures containing pendant rather than bridged organofunctionality were synthesized. Surfaces modified with pendant dipodal silanes were found to be more resistant to hydrolysis than the bridged structure with single-carbon separated (disilapropyl)silanes, demonstrating the greatest resistance to hydrolysis and best stability (see figure).

Processes for manufacturing organochlorosilanes and dipodal silanes and silanes made thereby

Processes are provided for producing organchlorosilanes and dipodal silanes in which an organic halide or alkene or chloralkene is reacted with a hydridochlorosilane in the presence of a quarternary phosphonium salt catalyst by providing sufficient heat to effect a dehydrohalogenative coupling reaction and/or a hydrosilylation reaction and venting the reaction to control reaction pressure and to remove gaseous byproducts from the reaction. The processes are preferably continuous using a catalyst in fluid form at reaction pressures not exceeding about 600 psi. The reactions may be carried out substantially isothermally and/or isobarically, for example in a plug flow reactor or continuous stirred tank reactor. The processes may produce novel silylated compounds including 1,2-bis(trichlorosilyl)decane or 1,2-bis(trimethoxysilyl)decane.