86210-91-5Relevant articles and documents
Visible-light-promoted iminyl-radical formation from Acyl oximes: A unified approach to pyridines, quinolines, and phenanthridines
Jiang, Heng,An, Xiaode,Tong, Kun,Zheng, Tianyi,Zhang, Yan,Yu, Shouyun
supporting information, p. 4055 - 4059 (2015/03/30)
A unified strategy involving visible-light-induced iminyl-radical formation has been established for the construction of pyridines, quinolines, and phenanthridines from acyl oximes. With fac-[Ir(ppy)3] as a photoredox catalyst, the acyl oximes were converted by 1 e- reduction into iminyl radical intermediates, which then underwent intramolecular homolytic aromatic substitution (HAS) to give the N-containing arenes. These reactions proceeded with a broad range of substrates at room temperature in high yield. This strategy of visible-light-induced iminyl-radical formation was successfully applied to a five-step concise synthesis of benzo[c]phenanthridine alkaloids.
SYNTHESIS OF SUBSTITUTED QUINOLINES BY REACTION OF THE VILSMEIER REAGENT WITH ANILINOBUTENOATES
Adams, David,Dominguez, Jose,Russo, Vicente Lo,Rekowski, Norma Morante De
, p. 281 - 284 (2007/10/02)
The synthesis of substituted quinolines by the reaction of the Vilsmeier reagent prepared from phosphorus oxychloride and dimethylformamide with anilinobutenoates is reported.A plausible mechanism for the formation of the quinolines is suggested.
A "ONE-POT" SYNTHESIS OF SUBSTITUTED 3-CARBOETHOXY-2-METHYLQUINOLINES FROM ETHYL ACETOACETATE
Adams, David R.,Colman, Trina de Saizarbitoria
, p. 1647 - 1654 (2007/10/02)
A "one-pot" synthesis of 3-carboethoxy-2-methylquinolines from ethyl acetoacetate via successive reaction with Vilsmeier reagent and anilines is described.
SYNTHESIS OF QUINOLINES BY REACTION OF ANILINOBUTENOATES WITH VILSMEIER REAGENT
Adams, David R.,Dominguez, Jose N.,Perez, Julio A.
, p. 517 - 518 (2007/10/02)
The synthesis of substituted carboethoxyquinolines is described by the reaction of ethylanilinobutenoates with Vilsmeier reagent.
