Palladium-catalysed cyclisation of N-alkynyl aminomalonates
Go around in (hetero)cycles! The palladium-catalysed tandem cyclisation/coupling reaction of alkynyl- and alkenyl-substituted aminomalonates leads to highly functionalised pyrrolidines and piperidines in good yield (see scheme). The reaction allows efficient access to a broad range of synthetically valuable building blocks.
Hess, Wilfried,Burton, Jonathan W.
supporting information; experimental part
p. 12303 - 12306
(2011/02/23)
N,N-Bis(trimethylsilyl)aminomethylierung von Grignard-Verbindungen - eine variable Aminsynthese
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Bestmann, Hans Juergen,Woelfel, Gerhard
p. 52
(2007/10/02)
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