88773-80-2Relevant articles and documents
Trimethylsilyl protection of alcohols over phosphorus pentoxide supported on silica gel
Shaterian, Hamid Reza,Fahimi, Nafiseh,Azizi, Kobra
experimental part, p. 1604 - 1611 (2011/10/05)
An eco-friendly and mild protocol for trimethylsilyl protection of alcohols over phosphorus pentoxide supported on silica gel using hexamethyldisilazane has been described. Solvent-free and ambient reaction conditions, easy workup, short reaction times, e
Reaction of carbonyl compounds with trialkylsilyl phenylselenide and tributylstannyl hydride under radical conditions
Nishiyama, Yutaka,Kajimoto, Hiroyuki,Kotani, Kazuya,Nishida, Takuma,Sonoda, Noboru
, p. 5696 - 5700 (2007/10/03)
A novel method for the hydrosilylation of carbonyl compounds has been developed. When carbonyl compounds were allowed to react with trimethylsilyl phenylselenide and tributylstannyl hydride in the presence of a catalytic amount of AIBN as the radical initiator, hydrosilylation of the carbonyl compounds efficiently proceeded to give the corresponding silyl ethers in moderate to good yields. In the absence of carbonyl compounds, the triethylsilyl hydride was obtained by the reaction of PhSeSiEt3 with Bu3SnH. Although the tributylgermyl phenylselenide instead of PhSeSiMe3 was treated with tributylstannyl hydride in the presence of a benzaldehyde under radical conditions, hydrogermylated product was not obtained and tributylgermyl hydride was mainly formed.
Hydrosilylation of carbonyl compounds using a PhSeSiMe3/Bu3SnH/AIBN system
Nishiyama, Yutaka,Kajimoto, Hiroyuki,Kotani, Kazuya,Sonoda, Noboru
, p. 3087 - 3089 (2007/10/03)
(equation presented) When carbonyl compounds were allowed to react with phenyl trimethylsilyl selenide and tributylstannyl hydride in the presence of a catalytic amount of AIBN as a radical initiator, the hydrosilylation of the carbonyl compounds efficiently proceeded to give the corresponding silyl ethers in moderate to good yields.
LITHIUM DIISOPROPYLAMIDE AS A HYDRIDE DONOR. REDUCTION OF ALDEHYDES.
Majewski, Marek
, p. 4057 - 4060 (2007/10/02)
Lithium diisopropylamide reduces aldehydes to the corresponding alcohols and also forms adducts with aldehydes.Both processes can compete with enolization.
