93189-07-2

Basic information

• Product Name: CHEMBRDG-BB 9071633
• Synonyms: CHEMBRDG-BB 9071633;3-(ANILINOMETHYL)PHENOL;UKRORGSYN-BB BBV-118836;3-(anilinomethyl)phenol(SALTDATA: FREE)
• CAS NO: 93189-07-2
• Molecular Formula: C₁₃H₁₃NO
• Molecular Weight: 199.252
• Mol File: 93189-07-2.mol

Chemical Properties

• Boiling Point: 374.3°C at 760 mmHg
• Flash Point: 163.3°C
• Appearance: /
• Density: 1.185g/cm³
• Vapor Pressure: 3.92E-06mmHg at 25°C
• Refractive Index: 1.662
• CAS DataBase Reference: CHEMBRDG-BB 9071633(CAS DataBase Reference)
• NIST Chemistry Reference: CHEMBRDG-BB 9071633(93189-07-2)
• EPA Substance Registry System: CHEMBRDG-BB 9071633(93189-07-2)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• Hazardous Substances Data: 93189-07-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H13NO/c15-13-8-4-5-11(9-13)10-14-12-6-2-1-3-7-12/h1-9,14-15H,10H2

Upstream product

• 100-83-4 meta-hydroxybenzaldehyde 
• 27559-45-1 3-hydroxy-N-phenyl-benzamide 
• 13206-60-5 N-(m-hydroxybenzylidene)aniline 
• 33542-73-3 N-(3-Hydroxy-benzyl)-N-phenyl-formamide 

Downstream Products

• 1612896-30-6 methyl 4-((3-((phenylamino)methyl)phenoxy)-methyl)benzoate 
• 929290-42-6 4-chloro-3-(3-phenylaminomethyl-phenoxymethyl)-thieno[3,2-c]pyridine-7-carboxylic acid ethyl ester 

Relevant articles and documents

Transfer hydrogenation of aldehydes and ketones catalyzed using an aminophosphinite POCNHpincer complex of Ni(ii)

The aminophosphinite pincer complex (POCNH)NiBr was found to effectively catalyze the transfer hydrogenation of aldehydes and ketones with 2-propanol and KOtBu as a base, presenting a rare example of bifunctional nickel transfer hydrogenation catalysts. The transfer hydrogenation of aldehydes and ketones was found to be selective, tolerating a wide range of other functional groups, including those prone to reduction, such as esters, amides, alkenes, pyridines, and nitriles. The reactions were suggested to proceedviathe metal-ligand cooperative mechanism with an intermediacy of an amido (POCN)NiIIspecies.

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